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C—H⋯π packing interactions in 2-[5,5-bis(4-benzyloxyphenyl)-3-cyano-4-methyl-2,5-dihydrofuran-2-ylidene]malononitrile
The title molecule, C(35)H(25)N(3)O(3), packs utilizing C—H⋯π attractive interactions causing the identical 4-benzyloxyphenyl groups to pack with different conformational angles. This difference is consistent with the variable interplanar dihedral angles found in closely related structures....
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247440/ https://www.ncbi.nlm.nih.gov/pubmed/22220058 http://dx.doi.org/10.1107/S1600536811043480 |
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author | Gainsford, Graeme J. Anderson, Jack Bhuiyan, M. Delower H. Kay, Andrew J. |
author_facet | Gainsford, Graeme J. Anderson, Jack Bhuiyan, M. Delower H. Kay, Andrew J. |
author_sort | Gainsford, Graeme J. |
collection | PubMed |
description | The title molecule, C(35)H(25)N(3)O(3), packs utilizing C—H⋯π attractive interactions causing the identical 4-benzyloxyphenyl groups to pack with different conformational angles. This difference is consistent with the variable interplanar dihedral angles found in closely related structures. |
format | Online Article Text |
id | pubmed-3247440 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32474402012-01-04 C—H⋯π packing interactions in 2-[5,5-bis(4-benzyloxyphenyl)-3-cyano-4-methyl-2,5-dihydrofuran-2-ylidene]malononitrile Gainsford, Graeme J. Anderson, Jack Bhuiyan, M. Delower H. Kay, Andrew J. Acta Crystallogr Sect E Struct Rep Online Organic Papers The title molecule, C(35)H(25)N(3)O(3), packs utilizing C—H⋯π attractive interactions causing the identical 4-benzyloxyphenyl groups to pack with different conformational angles. This difference is consistent with the variable interplanar dihedral angles found in closely related structures. International Union of Crystallography 2011-10-29 /pmc/articles/PMC3247440/ /pubmed/22220058 http://dx.doi.org/10.1107/S1600536811043480 Text en © Gainsford et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Gainsford, Graeme J. Anderson, Jack Bhuiyan, M. Delower H. Kay, Andrew J. C—H⋯π packing interactions in 2-[5,5-bis(4-benzyloxyphenyl)-3-cyano-4-methyl-2,5-dihydrofuran-2-ylidene]malononitrile |
title | C—H⋯π packing interactions in 2-[5,5-bis(4-benzyloxyphenyl)-3-cyano-4-methyl-2,5-dihydrofuran-2-ylidene]malononitrile |
title_full | C—H⋯π packing interactions in 2-[5,5-bis(4-benzyloxyphenyl)-3-cyano-4-methyl-2,5-dihydrofuran-2-ylidene]malononitrile |
title_fullStr | C—H⋯π packing interactions in 2-[5,5-bis(4-benzyloxyphenyl)-3-cyano-4-methyl-2,5-dihydrofuran-2-ylidene]malononitrile |
title_full_unstemmed | C—H⋯π packing interactions in 2-[5,5-bis(4-benzyloxyphenyl)-3-cyano-4-methyl-2,5-dihydrofuran-2-ylidene]malononitrile |
title_short | C—H⋯π packing interactions in 2-[5,5-bis(4-benzyloxyphenyl)-3-cyano-4-methyl-2,5-dihydrofuran-2-ylidene]malononitrile |
title_sort | c—h⋯π packing interactions in 2-[5,5-bis(4-benzyloxyphenyl)-3-cyano-4-methyl-2,5-dihydrofuran-2-ylidene]malononitrile |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247440/ https://www.ncbi.nlm.nih.gov/pubmed/22220058 http://dx.doi.org/10.1107/S1600536811043480 |
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