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C—H⋯π packing inter­actions in 2-[5,5-bis­(4-benzyl­oxyphen­yl)-3-cyano-4-methyl-2,5-dihydro­furan-2-yl­idene]malononitrile

The title mol­ecule, C(35)H(25)N(3)O(3), packs utilizing C—H⋯π attractive inter­actions causing the identical 4-benzyl­oxyphenyl groups to pack with different conformational angles. This difference is consistent with the variable inter­planar dihedral angles found in closely related structures....

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Detalles Bibliográficos
Autores principales: Gainsford, Graeme J., Anderson, Jack, Bhuiyan, M. Delower H., Kay, Andrew J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247440/
https://www.ncbi.nlm.nih.gov/pubmed/22220058
http://dx.doi.org/10.1107/S1600536811043480
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author Gainsford, Graeme J.
Anderson, Jack
Bhuiyan, M. Delower H.
Kay, Andrew J.
author_facet Gainsford, Graeme J.
Anderson, Jack
Bhuiyan, M. Delower H.
Kay, Andrew J.
author_sort Gainsford, Graeme J.
collection PubMed
description The title mol­ecule, C(35)H(25)N(3)O(3), packs utilizing C—H⋯π attractive inter­actions causing the identical 4-benzyl­oxyphenyl groups to pack with different conformational angles. This difference is consistent with the variable inter­planar dihedral angles found in closely related structures.
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spelling pubmed-32474402012-01-04 C—H⋯π packing inter­actions in 2-[5,5-bis­(4-benzyl­oxyphen­yl)-3-cyano-4-methyl-2,5-dihydro­furan-2-yl­idene]malononitrile Gainsford, Graeme J. Anderson, Jack Bhuiyan, M. Delower H. Kay, Andrew J. Acta Crystallogr Sect E Struct Rep Online Organic Papers The title mol­ecule, C(35)H(25)N(3)O(3), packs utilizing C—H⋯π attractive inter­actions causing the identical 4-benzyl­oxyphenyl groups to pack with different conformational angles. This difference is consistent with the variable inter­planar dihedral angles found in closely related structures. International Union of Crystallography 2011-10-29 /pmc/articles/PMC3247440/ /pubmed/22220058 http://dx.doi.org/10.1107/S1600536811043480 Text en © Gainsford et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Gainsford, Graeme J.
Anderson, Jack
Bhuiyan, M. Delower H.
Kay, Andrew J.
C—H⋯π packing inter­actions in 2-[5,5-bis­(4-benzyl­oxyphen­yl)-3-cyano-4-methyl-2,5-dihydro­furan-2-yl­idene]malononitrile
title C—H⋯π packing inter­actions in 2-[5,5-bis­(4-benzyl­oxyphen­yl)-3-cyano-4-methyl-2,5-dihydro­furan-2-yl­idene]malononitrile
title_full C—H⋯π packing inter­actions in 2-[5,5-bis­(4-benzyl­oxyphen­yl)-3-cyano-4-methyl-2,5-dihydro­furan-2-yl­idene]malononitrile
title_fullStr C—H⋯π packing inter­actions in 2-[5,5-bis­(4-benzyl­oxyphen­yl)-3-cyano-4-methyl-2,5-dihydro­furan-2-yl­idene]malononitrile
title_full_unstemmed C—H⋯π packing inter­actions in 2-[5,5-bis­(4-benzyl­oxyphen­yl)-3-cyano-4-methyl-2,5-dihydro­furan-2-yl­idene]malononitrile
title_short C—H⋯π packing inter­actions in 2-[5,5-bis­(4-benzyl­oxyphen­yl)-3-cyano-4-methyl-2,5-dihydro­furan-2-yl­idene]malononitrile
title_sort c—h⋯π packing inter­actions in 2-[5,5-bis­(4-benzyl­oxyphen­yl)-3-cyano-4-methyl-2,5-dihydro­furan-2-yl­idene]malononitrile
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247440/
https://www.ncbi.nlm.nih.gov/pubmed/22220058
http://dx.doi.org/10.1107/S1600536811043480
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