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Benzene-1,4-diol–5-(1H-imidazol-1-yl)pyrimidine (1/1)
The asymmetric unit of title compound, C(7)H(6)N(4)·C(6)H(6)O(2), contains one 5-(1H-imidazol-1-yl)pyrimidine molecule and two half benzene-1,4-diol molecules; the benzene-1,4-diol molecules are located on individual inversion centers. In the pyrimidine molecule, the imidazole ring is twisted wi...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247463/ https://www.ncbi.nlm.nih.gov/pubmed/22220081 http://dx.doi.org/10.1107/S1600536811043819 |
Sumario: | The asymmetric unit of title compound, C(7)H(6)N(4)·C(6)H(6)O(2), contains one 5-(1H-imidazol-1-yl)pyrimidine molecule and two half benzene-1,4-diol molecules; the benzene-1,4-diol molecules are located on individual inversion centers. In the pyrimidine molecule, the imidazole ring is twisted with respect to the pyrimidine ring at a dihedral angle of 25.73 (7)°. In the crystal, O—H⋯N hydrogen bonds link the molecules to form supramolecular chains. π–π stacking is also observed in the crystal, the centroid–centroid distance between parallel imdazole rings being 3.5543 (16) Å. |
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