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(E)-1-(Thio­phen-2-yl)-3-(2,4,6-tri­meth­oxy­phen­yl)prop-2-en-1-one

There are two crystallograpically independent mol­ecules in the asymmetric unit of the title heteroaryl chalcone derivative, C(16)H(16)O(4)S, with slightly different conformations. The thienyl ring of one mol­ecule is disordered over two positions, with a refined site-occupancy ratio of 0.713 (5):0....

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Detalles Bibliográficos
Autores principales: Fun, Hoong-Kun, Suwunwong, Thitipone, Anantapong, Teerasak, Karalai, Chatchanok, Chantrapromma, Suchada
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247464/
https://www.ncbi.nlm.nih.gov/pubmed/22220082
http://dx.doi.org/10.1107/S1600536811042930
Descripción
Sumario:There are two crystallograpically independent mol­ecules in the asymmetric unit of the title heteroaryl chalcone derivative, C(16)H(16)O(4)S, with slightly different conformations. The thienyl ring of one mol­ecule is disordered over two positions, with a refined site-occupancy ratio of 0.713 (5):0.287 (5). The mol­ecules are twisted: the dihedral angle between the thienyl and benzene rings is 9.72 (19)° in the ordered mol­ecule, and 3.8 (4) and 2.1 (8)° for the major and minor components, respectively, in the disordered mol­ecule. In both mol­ecules, all three substituted meth­oxy groups are coplanar with the benzene ring to which they are attached. In each mol­ecule, a weak intra­molecular C—H⋯O inter­action generates an S(6) ring motif. In the crystal structure, adjacent mol­ecules are linked into a three-dimensional network by weak C—H⋯O inter­actions.