4-Methyl-N-(3-methyl­phen­yl)pyridin-2-amine

The title amine, C(13)H(14)N(2), is twisted with a dihedral angle between the rings of 60.07 (9)°. The amine N—H group and pyridine N atom are syn allowing for the formation of centrosymmetric eight-membered {⋯HNCN}(2) synthons via N—H⋯N hydrogen bonds. The two-mol­ecule aggregates are sustained in...

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Autores principales: Fairuz, Zainal Abidin, Aiyub, Zaharah, Abdullah, Zanariah, Ng, Seik Weng, Tiekink, Edward R. T.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247467/
https://www.ncbi.nlm.nih.gov/pubmed/22220085
http://dx.doi.org/10.1107/S1600536811044059
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author Fairuz, Zainal Abidin
Aiyub, Zaharah
Abdullah, Zanariah
Ng, Seik Weng
Tiekink, Edward R. T.
author_facet Fairuz, Zainal Abidin
Aiyub, Zaharah
Abdullah, Zanariah
Ng, Seik Weng
Tiekink, Edward R. T.
author_sort Fairuz, Zainal Abidin
collection PubMed
description The title amine, C(13)H(14)N(2), is twisted with a dihedral angle between the rings of 60.07 (9)°. The amine N—H group and pyridine N atom are syn allowing for the formation of centrosymmetric eight-membered {⋯HNCN}(2) synthons via N—H⋯N hydrogen bonds. The two-mol­ecule aggregates are sustained in the three-dimensional crystal packing via C—H⋯π and π–π inter­actions [centroid–centroid distance for pyridyl rings = 3.7535 (12) Å]
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spelling pubmed-32474672012-01-04 4-Methyl-N-(3-methyl­phen­yl)pyridin-2-amine Fairuz, Zainal Abidin Aiyub, Zaharah Abdullah, Zanariah Ng, Seik Weng Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Organic Papers The title amine, C(13)H(14)N(2), is twisted with a dihedral angle between the rings of 60.07 (9)°. The amine N—H group and pyridine N atom are syn allowing for the formation of centrosymmetric eight-membered {⋯HNCN}(2) synthons via N—H⋯N hydrogen bonds. The two-mol­ecule aggregates are sustained in the three-dimensional crystal packing via C—H⋯π and π–π inter­actions [centroid–centroid distance for pyridyl rings = 3.7535 (12) Å] International Union of Crystallography 2011-10-29 /pmc/articles/PMC3247467/ /pubmed/22220085 http://dx.doi.org/10.1107/S1600536811044059 Text en © Fairuz et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Fairuz, Zainal Abidin
Aiyub, Zaharah
Abdullah, Zanariah
Ng, Seik Weng
Tiekink, Edward R. T.
4-Methyl-N-(3-methyl­phen­yl)pyridin-2-amine
title 4-Methyl-N-(3-methyl­phen­yl)pyridin-2-amine
title_full 4-Methyl-N-(3-methyl­phen­yl)pyridin-2-amine
title_fullStr 4-Methyl-N-(3-methyl­phen­yl)pyridin-2-amine
title_full_unstemmed 4-Methyl-N-(3-methyl­phen­yl)pyridin-2-amine
title_short 4-Methyl-N-(3-methyl­phen­yl)pyridin-2-amine
title_sort 4-methyl-n-(3-methyl­phen­yl)pyridin-2-amine
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247467/
https://www.ncbi.nlm.nih.gov/pubmed/22220085
http://dx.doi.org/10.1107/S1600536811044059
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AT ngseikweng 4methyln3methylphenylpyridin2amine
AT tiekinkedwardrt 4methyln3methylphenylpyridin2amine

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