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2-(Naphthalen-2-yloxy)-5-nitropyridine
A nearly orthogonal relationship is found for the ring systems in the title compound, C(15)H(10)N(2)O(3), with the dihedral angle between the rings being 86.13 (11)°. The nitro group is approximately coplanar with the pyridine ring to which it is connected [the O—N—C—C torsion angle = −1.8 (4)°]. Th...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247468/ https://www.ncbi.nlm.nih.gov/pubmed/22220086 http://dx.doi.org/10.1107/S1600536811044060 |
Sumario: | A nearly orthogonal relationship is found for the ring systems in the title compound, C(15)H(10)N(2)O(3), with the dihedral angle between the rings being 86.13 (11)°. The nitro group is approximately coplanar with the pyridine ring to which it is connected [the O—N—C—C torsion angle = −1.8 (4)°]. This coplanarity allows for the close approach of these residues in the crystal structure enabling the formation of N—O⋯π(pyridine) interactions [3.547 (4) Å]. Further consolidation of the crystal packing is afforded by weak π–π interactions [centroid–centroid distances = 3.9576 (16) and 3.9822 (16) Å]. |
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