2-(Naphthalen-2-yl­oxy)-5-nitro­pyridine

A nearly orthogonal relationship is found for the ring systems in the title compound, C(15)H(10)N(2)O(3), with the dihedral angle between the rings being 86.13 (11)°. The nitro group is approximately coplanar with the pyridine ring to which it is connected [the O—N—C—C torsion angle = −1.8 (4)°]. Th...

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Detalles Bibliográficos
Autores principales: Nasir, Shah Bakhtiar, Fairuz, Zainal Abidin, Abdullah, Zanariah, Ng, Seik Weng, Tiekink, Edward R. T.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247468/
https://www.ncbi.nlm.nih.gov/pubmed/22220086
http://dx.doi.org/10.1107/S1600536811044060
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author Nasir, Shah Bakhtiar
Fairuz, Zainal Abidin
Abdullah, Zanariah
Ng, Seik Weng
Tiekink, Edward R. T.
author_facet Nasir, Shah Bakhtiar
Fairuz, Zainal Abidin
Abdullah, Zanariah
Ng, Seik Weng
Tiekink, Edward R. T.
author_sort Nasir, Shah Bakhtiar
collection PubMed
description A nearly orthogonal relationship is found for the ring systems in the title compound, C(15)H(10)N(2)O(3), with the dihedral angle between the rings being 86.13 (11)°. The nitro group is approximately coplanar with the pyridine ring to which it is connected [the O—N—C—C torsion angle = −1.8 (4)°]. This coplanarity allows for the close approach of these residues in the crystal structure enabling the formation of N—O⋯π(pyridine) inter­actions [3.547 (4) Å]. Further consolidation of the crystal packing is afforded by weak π–π inter­actions [centroid–centroid distances = 3.9576 (16) and 3.9822 (16) Å].
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spelling pubmed-32474682012-01-04 2-(Naphthalen-2-yl­oxy)-5-nitro­pyridine Nasir, Shah Bakhtiar Fairuz, Zainal Abidin Abdullah, Zanariah Ng, Seik Weng Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Organic Papers A nearly orthogonal relationship is found for the ring systems in the title compound, C(15)H(10)N(2)O(3), with the dihedral angle between the rings being 86.13 (11)°. The nitro group is approximately coplanar with the pyridine ring to which it is connected [the O—N—C—C torsion angle = −1.8 (4)°]. This coplanarity allows for the close approach of these residues in the crystal structure enabling the formation of N—O⋯π(pyridine) inter­actions [3.547 (4) Å]. Further consolidation of the crystal packing is afforded by weak π–π inter­actions [centroid–centroid distances = 3.9576 (16) and 3.9822 (16) Å]. International Union of Crystallography 2011-10-29 /pmc/articles/PMC3247468/ /pubmed/22220086 http://dx.doi.org/10.1107/S1600536811044060 Text en © Nasir et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Nasir, Shah Bakhtiar
Fairuz, Zainal Abidin
Abdullah, Zanariah
Ng, Seik Weng
Tiekink, Edward R. T.
2-(Naphthalen-2-yl­oxy)-5-nitro­pyridine
title 2-(Naphthalen-2-yl­oxy)-5-nitro­pyridine
title_full 2-(Naphthalen-2-yl­oxy)-5-nitro­pyridine
title_fullStr 2-(Naphthalen-2-yl­oxy)-5-nitro­pyridine
title_full_unstemmed 2-(Naphthalen-2-yl­oxy)-5-nitro­pyridine
title_short 2-(Naphthalen-2-yl­oxy)-5-nitro­pyridine
title_sort 2-(naphthalen-2-yl­oxy)-5-nitro­pyridine
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247468/
https://www.ncbi.nlm.nih.gov/pubmed/22220086
http://dx.doi.org/10.1107/S1600536811044060
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AT abdullahzanariah 2naphthalen2yloxy5nitropyridine
AT ngseikweng 2naphthalen2yloxy5nitropyridine
AT tiekinkedwardrt 2naphthalen2yloxy5nitropyridine

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