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(E)-1-(2,4-Dinitrophenyl)-2-[1-(2-nitrophenyl)ethylidene]hydrazine
The title compound, C(14)H(11)N(5)O(6), was obtained from the condensation reaction of 2,4-dinitrophenylhydrazine and 2-nitroacetophenone. The molecule displays an E conformation about the C=N double bond and an intramolecular N—H⋯O hydrogen bond generates an S(6) ring motif. The dihedral angle...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247472/ https://www.ncbi.nlm.nih.gov/pubmed/22220090 http://dx.doi.org/10.1107/S1600536811042620 |
Sumario: | The title compound, C(14)H(11)N(5)O(6), was obtained from the condensation reaction of 2,4-dinitrophenylhydrazine and 2-nitroacetophenone. The molecule displays an E conformation about the C=N double bond and an intramolecular N—H⋯O hydrogen bond generates an S(6) ring motif. The dihedral angle between the benzene rings is 7.84 (6)°. In the crystal, molecules are linked by C—H⋯O hydrogen bonds and π–π stacking interactions [centroid–centroid distance = 3.6447 (8) Å] into a three-dimensional network. |
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