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(E)-1-(2,4-Dinitro­phen­yl)-2-[1-(2-nitro­phen­yl)ethyl­idene]hydrazine

The title compound, C(14)H(11)N(5)O(6), was obtained from the condensation reaction of 2,4-dinitro­phenyl­hydrazine and 2-nitro­acetophenone. The mol­ecule displays an E conformation about the C=N double bond and an intra­molecular N—H⋯O hydrogen bond generates an S(6) ring motif. The dihedral angle...

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Detalles Bibliográficos
Autores principales: Nilwanna, Boonlerd, Chantrapromma, Suchada, Jansrisewangwong, Patcharaporn, Fun, Hoong-Kun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247472/
https://www.ncbi.nlm.nih.gov/pubmed/22220090
http://dx.doi.org/10.1107/S1600536811042620
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author Nilwanna, Boonlerd
Chantrapromma, Suchada
Jansrisewangwong, Patcharaporn
Fun, Hoong-Kun
author_facet Nilwanna, Boonlerd
Chantrapromma, Suchada
Jansrisewangwong, Patcharaporn
Fun, Hoong-Kun
author_sort Nilwanna, Boonlerd
collection PubMed
description The title compound, C(14)H(11)N(5)O(6), was obtained from the condensation reaction of 2,4-dinitro­phenyl­hydrazine and 2-nitro­acetophenone. The mol­ecule displays an E conformation about the C=N double bond and an intra­molecular N—H⋯O hydrogen bond generates an S(6) ring motif. The dihedral angle between the benzene rings is 7.84 (6)°. In the crystal, mol­ecules are linked by C—H⋯O hydrogen bonds and π–π stacking inter­actions [centroid–centroid distance = 3.6447 (8) Å] into a three-dimensional network.
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spelling pubmed-32474722012-01-04 (E)-1-(2,4-Dinitro­phen­yl)-2-[1-(2-nitro­phen­yl)ethyl­idene]hydrazine Nilwanna, Boonlerd Chantrapromma, Suchada Jansrisewangwong, Patcharaporn Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(14)H(11)N(5)O(6), was obtained from the condensation reaction of 2,4-dinitro­phenyl­hydrazine and 2-nitro­acetophenone. The mol­ecule displays an E conformation about the C=N double bond and an intra­molecular N—H⋯O hydrogen bond generates an S(6) ring motif. The dihedral angle between the benzene rings is 7.84 (6)°. In the crystal, mol­ecules are linked by C—H⋯O hydrogen bonds and π–π stacking inter­actions [centroid–centroid distance = 3.6447 (8) Å] into a three-dimensional network. International Union of Crystallography 2011-10-29 /pmc/articles/PMC3247472/ /pubmed/22220090 http://dx.doi.org/10.1107/S1600536811042620 Text en © Nilwanna et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Nilwanna, Boonlerd
Chantrapromma, Suchada
Jansrisewangwong, Patcharaporn
Fun, Hoong-Kun
(E)-1-(2,4-Dinitro­phen­yl)-2-[1-(2-nitro­phen­yl)ethyl­idene]hydrazine
title (E)-1-(2,4-Dinitro­phen­yl)-2-[1-(2-nitro­phen­yl)ethyl­idene]hydrazine
title_full (E)-1-(2,4-Dinitro­phen­yl)-2-[1-(2-nitro­phen­yl)ethyl­idene]hydrazine
title_fullStr (E)-1-(2,4-Dinitro­phen­yl)-2-[1-(2-nitro­phen­yl)ethyl­idene]hydrazine
title_full_unstemmed (E)-1-(2,4-Dinitro­phen­yl)-2-[1-(2-nitro­phen­yl)ethyl­idene]hydrazine
title_short (E)-1-(2,4-Dinitro­phen­yl)-2-[1-(2-nitro­phen­yl)ethyl­idene]hydrazine
title_sort (e)-1-(2,4-dinitro­phen­yl)-2-[1-(2-nitro­phen­yl)ethyl­idene]hydrazine
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247472/
https://www.ncbi.nlm.nih.gov/pubmed/22220090
http://dx.doi.org/10.1107/S1600536811042620
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