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(E)-1-(2,4-Dinitrophenyl)-2-[1-(2-nitrophenyl)ethylidene]hydrazine
The title compound, C(14)H(11)N(5)O(6), was obtained from the condensation reaction of 2,4-dinitrophenylhydrazine and 2-nitroacetophenone. The molecule displays an E conformation about the C=N double bond and an intramolecular N—H⋯O hydrogen bond generates an S(6) ring motif. The dihedral angle...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247472/ https://www.ncbi.nlm.nih.gov/pubmed/22220090 http://dx.doi.org/10.1107/S1600536811042620 |
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author | Nilwanna, Boonlerd Chantrapromma, Suchada Jansrisewangwong, Patcharaporn Fun, Hoong-Kun |
author_facet | Nilwanna, Boonlerd Chantrapromma, Suchada Jansrisewangwong, Patcharaporn Fun, Hoong-Kun |
author_sort | Nilwanna, Boonlerd |
collection | PubMed |
description | The title compound, C(14)H(11)N(5)O(6), was obtained from the condensation reaction of 2,4-dinitrophenylhydrazine and 2-nitroacetophenone. The molecule displays an E conformation about the C=N double bond and an intramolecular N—H⋯O hydrogen bond generates an S(6) ring motif. The dihedral angle between the benzene rings is 7.84 (6)°. In the crystal, molecules are linked by C—H⋯O hydrogen bonds and π–π stacking interactions [centroid–centroid distance = 3.6447 (8) Å] into a three-dimensional network. |
format | Online Article Text |
id | pubmed-3247472 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32474722012-01-04 (E)-1-(2,4-Dinitrophenyl)-2-[1-(2-nitrophenyl)ethylidene]hydrazine Nilwanna, Boonlerd Chantrapromma, Suchada Jansrisewangwong, Patcharaporn Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(14)H(11)N(5)O(6), was obtained from the condensation reaction of 2,4-dinitrophenylhydrazine and 2-nitroacetophenone. The molecule displays an E conformation about the C=N double bond and an intramolecular N—H⋯O hydrogen bond generates an S(6) ring motif. The dihedral angle between the benzene rings is 7.84 (6)°. In the crystal, molecules are linked by C—H⋯O hydrogen bonds and π–π stacking interactions [centroid–centroid distance = 3.6447 (8) Å] into a three-dimensional network. International Union of Crystallography 2011-10-29 /pmc/articles/PMC3247472/ /pubmed/22220090 http://dx.doi.org/10.1107/S1600536811042620 Text en © Nilwanna et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Nilwanna, Boonlerd Chantrapromma, Suchada Jansrisewangwong, Patcharaporn Fun, Hoong-Kun (E)-1-(2,4-Dinitrophenyl)-2-[1-(2-nitrophenyl)ethylidene]hydrazine |
title | (E)-1-(2,4-Dinitrophenyl)-2-[1-(2-nitrophenyl)ethylidene]hydrazine |
title_full | (E)-1-(2,4-Dinitrophenyl)-2-[1-(2-nitrophenyl)ethylidene]hydrazine |
title_fullStr | (E)-1-(2,4-Dinitrophenyl)-2-[1-(2-nitrophenyl)ethylidene]hydrazine |
title_full_unstemmed | (E)-1-(2,4-Dinitrophenyl)-2-[1-(2-nitrophenyl)ethylidene]hydrazine |
title_short | (E)-1-(2,4-Dinitrophenyl)-2-[1-(2-nitrophenyl)ethylidene]hydrazine |
title_sort | (e)-1-(2,4-dinitrophenyl)-2-[1-(2-nitrophenyl)ethylidene]hydrazine |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247472/ https://www.ncbi.nlm.nih.gov/pubmed/22220090 http://dx.doi.org/10.1107/S1600536811042620 |
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