4-(2,6-Dibromo-4-fluoro­anilino)pent-3-en-2-one

The title enamino­ketone, C(11)H(10)Br(2)FNO, has a roughly planar pentenone chain; the maximum displacement of an atom from the pentenone plane is 0.071 (4) Å. The dihedral angle between the benzene ring and the pentenone unit is 77.2 (1)°. Inter­molecular C—H⋯Br and C—H⋯O inter­actions, as well as...

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Detalles Bibliográficos
Autores principales: Venter, Gertruida J.S., Steyl, Gideon, Roodt, Andreas
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247479/
https://www.ncbi.nlm.nih.gov/pubmed/22220097
http://dx.doi.org/10.1107/S1600536811044606
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author Venter, Gertruida J.S.
Steyl, Gideon
Roodt, Andreas
author_facet Venter, Gertruida J.S.
Steyl, Gideon
Roodt, Andreas
author_sort Venter, Gertruida J.S.
collection PubMed
description The title enamino­ketone, C(11)H(10)Br(2)FNO, has a roughly planar pentenone chain; the maximum displacement of an atom from the pentenone plane is 0.071 (4) Å. The dihedral angle between the benzene ring and the pentenone unit is 77.2 (1)°. Inter­molecular C—H⋯Br and C—H⋯O inter­actions, as well as an intra­molecular N—H⋯O inter­action, are observed. In both methyl groups, each H atom is disordered equally over two sites.
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spelling pubmed-32474792012-01-04 4-(2,6-Dibromo-4-fluoro­anilino)pent-3-en-2-one Venter, Gertruida J.S. Steyl, Gideon Roodt, Andreas Acta Crystallogr Sect E Struct Rep Online Organic Papers The title enamino­ketone, C(11)H(10)Br(2)FNO, has a roughly planar pentenone chain; the maximum displacement of an atom from the pentenone plane is 0.071 (4) Å. The dihedral angle between the benzene ring and the pentenone unit is 77.2 (1)°. Inter­molecular C—H⋯Br and C—H⋯O inter­actions, as well as an intra­molecular N—H⋯O inter­action, are observed. In both methyl groups, each H atom is disordered equally over two sites. International Union of Crystallography 2011-10-29 /pmc/articles/PMC3247479/ /pubmed/22220097 http://dx.doi.org/10.1107/S1600536811044606 Text en © Venter et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Venter, Gertruida J.S.
Steyl, Gideon
Roodt, Andreas
4-(2,6-Dibromo-4-fluoro­anilino)pent-3-en-2-one
title 4-(2,6-Dibromo-4-fluoro­anilino)pent-3-en-2-one
title_full 4-(2,6-Dibromo-4-fluoro­anilino)pent-3-en-2-one
title_fullStr 4-(2,6-Dibromo-4-fluoro­anilino)pent-3-en-2-one
title_full_unstemmed 4-(2,6-Dibromo-4-fluoro­anilino)pent-3-en-2-one
title_short 4-(2,6-Dibromo-4-fluoro­anilino)pent-3-en-2-one
title_sort 4-(2,6-dibromo-4-fluoro­anilino)pent-3-en-2-one
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247479/
https://www.ncbi.nlm.nih.gov/pubmed/22220097
http://dx.doi.org/10.1107/S1600536811044606
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