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Gallic acid pyridine monosolvate

In the title compound (systenatic name: 3,4,5-trihy­droxy­benzoic acid pyridine monosolvate), C(5)H(5)N·C(7)H(6)O(5), the gallic acid mol­ecule is essentially planar (r.m.s deviation = 0.0766 Å for non-H atoms) and is linked to the pyridine mol­ecule by an O—H⋯N hydrogen bond. An intra­molecular O—H...

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Detalles Bibliográficos
Autores principales: Dong, Fu-Yue, Wu, Jie, Tian, Hai-Yan, Ye, Qing-Mei, Jiang, Ren-Wang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247482/
https://www.ncbi.nlm.nih.gov/pubmed/22220100
http://dx.doi.org/10.1107/S1600536811043868
Descripción
Sumario:In the title compound (systenatic name: 3,4,5-trihy­droxy­benzoic acid pyridine monosolvate), C(5)H(5)N·C(7)H(6)O(5), the gallic acid mol­ecule is essentially planar (r.m.s deviation = 0.0766 Å for non-H atoms) and is linked to the pyridine mol­ecule by an O—H⋯N hydrogen bond. An intra­molecular O—H⋯O hydrogen bond occurs in the gallic acid mol­ecule. The gallic acid and pyridine mean planes make a dihedral angle 12.6 (3)°. Inter­molecular O—H⋯O and O—H⋯N hydrogen bonding involving the hy­droxy and carboxyl groups and the pyridine mol­ecule, and π–π inter­actions between inversion-related pyridines [centroid–centroid distance = 3.459 (6) Å] and between pyridine and benzene rings [centroid–centroid distance = 3.548 (6) Å], lead to a three-dimensional network in the crystal.