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Gallic acid pyridine monosolvate
In the title compound (systenatic name: 3,4,5-trihydroxybenzoic acid pyridine monosolvate), C(5)H(5)N·C(7)H(6)O(5), the gallic acid molecule is essentially planar (r.m.s deviation = 0.0766 Å for non-H atoms) and is linked to the pyridine molecule by an O—H⋯N hydrogen bond. An intramolecular O—H...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247482/ https://www.ncbi.nlm.nih.gov/pubmed/22220100 http://dx.doi.org/10.1107/S1600536811043868 |
Sumario: | In the title compound (systenatic name: 3,4,5-trihydroxybenzoic acid pyridine monosolvate), C(5)H(5)N·C(7)H(6)O(5), the gallic acid molecule is essentially planar (r.m.s deviation = 0.0766 Å for non-H atoms) and is linked to the pyridine molecule by an O—H⋯N hydrogen bond. An intramolecular O—H⋯O hydrogen bond occurs in the gallic acid molecule. The gallic acid and pyridine mean planes make a dihedral angle 12.6 (3)°. Intermolecular O—H⋯O and O—H⋯N hydrogen bonding involving the hydroxy and carboxyl groups and the pyridine molecule, and π–π interactions between inversion-related pyridines [centroid–centroid distance = 3.459 (6) Å] and between pyridine and benzene rings [centroid–centroid distance = 3.548 (6) Å], lead to a three-dimensional network in the crystal. |
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