Thieno[3,4-d][1,3]dithiole-2-thione

In the title compound, C(5)H(2)S(4), the terminal monocyclic S atom deviates by 0.117 (1) Å from the mean plane of the other non-H atoms (r.m.s. deviation = 0.001 Å). All six C—S bonds and the central C—C bond in the rings are characterized by π-conjugated lengths, endowing the mol­ecule with high π...

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Detalles Bibliográficos
Autores principales: Wen, Hua-wen, Fang, Qi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247483/
https://www.ncbi.nlm.nih.gov/pubmed/22220101
http://dx.doi.org/10.1107/S1600536811044084
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author Wen, Hua-wen
Fang, Qi
author_facet Wen, Hua-wen
Fang, Qi
author_sort Wen, Hua-wen
collection PubMed
description In the title compound, C(5)H(2)S(4), the terminal monocyclic S atom deviates by 0.117 (1) Å from the mean plane of the other non-H atoms (r.m.s. deviation = 0.001 Å). All six C—S bonds and the central C—C bond in the rings are characterized by π-conjugated lengths, endowing the mol­ecule with high π-conjugation. In the crystal, the mol­ecules are parallel packed, forming columnar stacks along the a axis. Short inter­molecular S⋯S contacts [3.397 (1) and 3.486 (1) Å], are observed.
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spelling pubmed-32474832012-01-04 Thieno[3,4-d][1,3]dithiole-2-thione Wen, Hua-wen Fang, Qi Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(5)H(2)S(4), the terminal monocyclic S atom deviates by 0.117 (1) Å from the mean plane of the other non-H atoms (r.m.s. deviation = 0.001 Å). All six C—S bonds and the central C—C bond in the rings are characterized by π-conjugated lengths, endowing the mol­ecule with high π-conjugation. In the crystal, the mol­ecules are parallel packed, forming columnar stacks along the a axis. Short inter­molecular S⋯S contacts [3.397 (1) and 3.486 (1) Å], are observed. International Union of Crystallography 2011-10-29 /pmc/articles/PMC3247483/ /pubmed/22220101 http://dx.doi.org/10.1107/S1600536811044084 Text en © Wen and Fang 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Wen, Hua-wen
Fang, Qi
Thieno[3,4-d][1,3]dithiole-2-thione
title Thieno[3,4-d][1,3]dithiole-2-thione
title_full Thieno[3,4-d][1,3]dithiole-2-thione
title_fullStr Thieno[3,4-d][1,3]dithiole-2-thione
title_full_unstemmed Thieno[3,4-d][1,3]dithiole-2-thione
title_short Thieno[3,4-d][1,3]dithiole-2-thione
title_sort thieno[3,4-d][1,3]dithiole-2-thione
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247483/
https://www.ncbi.nlm.nih.gov/pubmed/22220101
http://dx.doi.org/10.1107/S1600536811044084
work_keys_str_mv AT wenhuawen thieno34d13dithiole2thione
AT fangqi thieno34d13dithiole2thione

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