2-Amino-4-(2-chloro­phen­yl)-5-oxo-5,6,7,8-tetra­hydro-4H-chromene-3-carbonitrile ethanol monosolvate

In the title compound, C(16)H(13)ClN(2)O(2)·C(2)H(6)O, the fused cyclo­hexene and pyran rings adopt envelope and flattened boat conformations, respectively. In the crystal, N—H⋯O and O—H⋯O hydrogen bonds link the chromene and ethanol solvent mol­ecules into infinite chains along the c axis, and N—H⋯...

Descripción completa

Detalles Bibliográficos
Autores principales: Qiao, Yan, Kong, Lingqian, Chen, Guifang, Li, Shengli, Gao, Zhiqing
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247485/
https://www.ncbi.nlm.nih.gov/pubmed/22220103
http://dx.doi.org/10.1107/S1600536811043650
_version_ 1782220117966323712
author Qiao, Yan
Kong, Lingqian
Chen, Guifang
Li, Shengli
Gao, Zhiqing
author_facet Qiao, Yan
Kong, Lingqian
Chen, Guifang
Li, Shengli
Gao, Zhiqing
author_sort Qiao, Yan
collection PubMed
description In the title compound, C(16)H(13)ClN(2)O(2)·C(2)H(6)O, the fused cyclo­hexene and pyran rings adopt envelope and flattened boat conformations, respectively. In the crystal, N—H⋯O and O—H⋯O hydrogen bonds link the chromene and ethanol solvent mol­ecules into infinite chains along the c axis, and N—H⋯N hydrogen bonds link these chains into a three-dimensional framework. Weak C—H⋯π inter­actions are also present.
format Online
Article
Text
id pubmed-3247485
institution National Center for Biotechnology Information
language English
publishDate 2011
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-32474852012-01-04 2-Amino-4-(2-chloro­phen­yl)-5-oxo-5,6,7,8-tetra­hydro-4H-chromene-3-carbonitrile ethanol monosolvate Qiao, Yan Kong, Lingqian Chen, Guifang Li, Shengli Gao, Zhiqing Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(16)H(13)ClN(2)O(2)·C(2)H(6)O, the fused cyclo­hexene and pyran rings adopt envelope and flattened boat conformations, respectively. In the crystal, N—H⋯O and O—H⋯O hydrogen bonds link the chromene and ethanol solvent mol­ecules into infinite chains along the c axis, and N—H⋯N hydrogen bonds link these chains into a three-dimensional framework. Weak C—H⋯π inter­actions are also present. International Union of Crystallography 2011-10-29 /pmc/articles/PMC3247485/ /pubmed/22220103 http://dx.doi.org/10.1107/S1600536811043650 Text en © Qiao et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Qiao, Yan
Kong, Lingqian
Chen, Guifang
Li, Shengli
Gao, Zhiqing
2-Amino-4-(2-chloro­phen­yl)-5-oxo-5,6,7,8-tetra­hydro-4H-chromene-3-carbonitrile ethanol monosolvate
title 2-Amino-4-(2-chloro­phen­yl)-5-oxo-5,6,7,8-tetra­hydro-4H-chromene-3-carbonitrile ethanol monosolvate
title_full 2-Amino-4-(2-chloro­phen­yl)-5-oxo-5,6,7,8-tetra­hydro-4H-chromene-3-carbonitrile ethanol monosolvate
title_fullStr 2-Amino-4-(2-chloro­phen­yl)-5-oxo-5,6,7,8-tetra­hydro-4H-chromene-3-carbonitrile ethanol monosolvate
title_full_unstemmed 2-Amino-4-(2-chloro­phen­yl)-5-oxo-5,6,7,8-tetra­hydro-4H-chromene-3-carbonitrile ethanol monosolvate
title_short 2-Amino-4-(2-chloro­phen­yl)-5-oxo-5,6,7,8-tetra­hydro-4H-chromene-3-carbonitrile ethanol monosolvate
title_sort 2-amino-4-(2-chloro­phen­yl)-5-oxo-5,6,7,8-tetra­hydro-4h-chromene-3-carbonitrile ethanol monosolvate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247485/
https://www.ncbi.nlm.nih.gov/pubmed/22220103
http://dx.doi.org/10.1107/S1600536811043650
work_keys_str_mv AT qiaoyan 2amino42chlorophenyl5oxo5678tetrahydro4hchromene3carbonitrileethanolmonosolvate
AT konglingqian 2amino42chlorophenyl5oxo5678tetrahydro4hchromene3carbonitrileethanolmonosolvate
AT chenguifang 2amino42chlorophenyl5oxo5678tetrahydro4hchromene3carbonitrileethanolmonosolvate
AT lishengli 2amino42chlorophenyl5oxo5678tetrahydro4hchromene3carbonitrileethanolmonosolvate
AT gaozhiqing 2amino42chlorophenyl5oxo5678tetrahydro4hchromene3carbonitrileethanolmonosolvate

Ejemplares similares