(E)-3-[3-(4-Bromo­phen­yl)-1-phenyl-1H-pyrazol-4-yl]-1-(2,4-dichloro­phen­yl)prop-2-en-1-one

In the title mol­ecule, C(24)H(15)BrCl(2)N(2)O, the dihedral angles betwen the pyrazole ring and its N-bonded phenyl (A) and C-bonded bromo­benzene (B) rings are 10.34 (16) and 40.95 (15)°, respectively. The dihedral angle between rings A and B is 56.89 (17)°. The title mol­ecule exists in a trans c...

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Detalles Bibliográficos
Autores principales: Fun, Hoong-Kun, Quah, Ching Kheng, Malladi, Shridhar, Isloor, Arun M., Shivananda, Kammasandra N.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247489/
https://www.ncbi.nlm.nih.gov/pubmed/22220107
http://dx.doi.org/10.1107/S1600536811044424
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author Fun, Hoong-Kun
Quah, Ching Kheng
Malladi, Shridhar
Isloor, Arun M.
Shivananda, Kammasandra N.
author_facet Fun, Hoong-Kun
Quah, Ching Kheng
Malladi, Shridhar
Isloor, Arun M.
Shivananda, Kammasandra N.
author_sort Fun, Hoong-Kun
collection PubMed
description In the title mol­ecule, C(24)H(15)BrCl(2)N(2)O, the dihedral angles betwen the pyrazole ring and its N-bonded phenyl (A) and C-bonded bromo­benzene (B) rings are 10.34 (16) and 40.95 (15)°, respectively. The dihedral angle between rings A and B is 56.89 (17)°. The title mol­ecule exists in a trans conformation with respect to the acyclic C=C bond. In the crystal, mol­ecules are linked into inversion dimers by pairs of C—H⋯O hydrogen bonds, generating R (2) (2)(14) loops. The crystal structure is further consolidated by C—H⋯π inter­actions.
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spelling pubmed-32474892012-01-04 (E)-3-[3-(4-Bromo­phen­yl)-1-phenyl-1H-pyrazol-4-yl]-1-(2,4-dichloro­phen­yl)prop-2-en-1-one Fun, Hoong-Kun Quah, Ching Kheng Malladi, Shridhar Isloor, Arun M. Shivananda, Kammasandra N. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title mol­ecule, C(24)H(15)BrCl(2)N(2)O, the dihedral angles betwen the pyrazole ring and its N-bonded phenyl (A) and C-bonded bromo­benzene (B) rings are 10.34 (16) and 40.95 (15)°, respectively. The dihedral angle between rings A and B is 56.89 (17)°. The title mol­ecule exists in a trans conformation with respect to the acyclic C=C bond. In the crystal, mol­ecules are linked into inversion dimers by pairs of C—H⋯O hydrogen bonds, generating R (2) (2)(14) loops. The crystal structure is further consolidated by C—H⋯π inter­actions. International Union of Crystallography 2011-10-29 /pmc/articles/PMC3247489/ /pubmed/22220107 http://dx.doi.org/10.1107/S1600536811044424 Text en © Fun et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Fun, Hoong-Kun
Quah, Ching Kheng
Malladi, Shridhar
Isloor, Arun M.
Shivananda, Kammasandra N.
(E)-3-[3-(4-Bromo­phen­yl)-1-phenyl-1H-pyrazol-4-yl]-1-(2,4-dichloro­phen­yl)prop-2-en-1-one
title (E)-3-[3-(4-Bromo­phen­yl)-1-phenyl-1H-pyrazol-4-yl]-1-(2,4-dichloro­phen­yl)prop-2-en-1-one
title_full (E)-3-[3-(4-Bromo­phen­yl)-1-phenyl-1H-pyrazol-4-yl]-1-(2,4-dichloro­phen­yl)prop-2-en-1-one
title_fullStr (E)-3-[3-(4-Bromo­phen­yl)-1-phenyl-1H-pyrazol-4-yl]-1-(2,4-dichloro­phen­yl)prop-2-en-1-one
title_full_unstemmed (E)-3-[3-(4-Bromo­phen­yl)-1-phenyl-1H-pyrazol-4-yl]-1-(2,4-dichloro­phen­yl)prop-2-en-1-one
title_short (E)-3-[3-(4-Bromo­phen­yl)-1-phenyl-1H-pyrazol-4-yl]-1-(2,4-dichloro­phen­yl)prop-2-en-1-one
title_sort (e)-3-[3-(4-bromo­phen­yl)-1-phenyl-1h-pyrazol-4-yl]-1-(2,4-dichloro­phen­yl)prop-2-en-1-one
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247489/
https://www.ncbi.nlm.nih.gov/pubmed/22220107
http://dx.doi.org/10.1107/S1600536811044424
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