3-(Trimethyl­sil­yl)prop-2-ynyl p-toluene­sulfonate

In the title compound, C(13)H(18)O(3)SSi, the SO(3) group displays a partial rotational (ca 50°) disorder about the C—S bond, with relative proportions 0.7744 (13):0.2256 (13). This disorder also forces the propynyl CH(2) group to be disordered.

Detalles Bibliográficos
Autores principales: Schmitt, Devin C., Morales, Guillermo A., Fronczek, Frank R., Watkins, Steven F.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247495/
https://www.ncbi.nlm.nih.gov/pubmed/22220113
http://dx.doi.org/10.1107/S1600536811043595
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author Schmitt, Devin C.
Morales, Guillermo A.
Fronczek, Frank R.
Watkins, Steven F.
author_facet Schmitt, Devin C.
Morales, Guillermo A.
Fronczek, Frank R.
Watkins, Steven F.
author_sort Schmitt, Devin C.
collection PubMed
description In the title compound, C(13)H(18)O(3)SSi, the SO(3) group displays a partial rotational (ca 50°) disorder about the C—S bond, with relative proportions 0.7744 (13):0.2256 (13). This disorder also forces the propynyl CH(2) group to be disordered.
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spelling pubmed-32474952012-01-04 3-(Trimethyl­sil­yl)prop-2-ynyl p-toluene­sulfonate Schmitt, Devin C. Morales, Guillermo A. Fronczek, Frank R. Watkins, Steven F. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(13)H(18)O(3)SSi, the SO(3) group displays a partial rotational (ca 50°) disorder about the C—S bond, with relative proportions 0.7744 (13):0.2256 (13). This disorder also forces the propynyl CH(2) group to be disordered. International Union of Crystallography 2011-10-29 /pmc/articles/PMC3247495/ /pubmed/22220113 http://dx.doi.org/10.1107/S1600536811043595 Text en © Schmitt et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Schmitt, Devin C.
Morales, Guillermo A.
Fronczek, Frank R.
Watkins, Steven F.
3-(Trimethyl­sil­yl)prop-2-ynyl p-toluene­sulfonate
title 3-(Trimethyl­sil­yl)prop-2-ynyl p-toluene­sulfonate
title_full 3-(Trimethyl­sil­yl)prop-2-ynyl p-toluene­sulfonate
title_fullStr 3-(Trimethyl­sil­yl)prop-2-ynyl p-toluene­sulfonate
title_full_unstemmed 3-(Trimethyl­sil­yl)prop-2-ynyl p-toluene­sulfonate
title_short 3-(Trimethyl­sil­yl)prop-2-ynyl p-toluene­sulfonate
title_sort 3-(trimethyl­sil­yl)prop-2-ynyl p-toluene­sulfonate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247495/
https://www.ncbi.nlm.nih.gov/pubmed/22220113
http://dx.doi.org/10.1107/S1600536811043595
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