4-[(2,4-Difluoro­phen­yl)hydrazinyl­idene]-3-methyl-5-oxo-4,5-dihydro-1H-pyrazole-1-carbothio­amide

In the title compound, C(11)H(9)F(2)N(5)OS, the pyrazole ring forms a dihedral angle of 16.42 (6)° with the benzene ring. Intra­molecular N—H⋯O hydrogen bonds generate two S(6) ring motifs. In the crystal, an R (2) (2)(8) ring motif is formed by a pair of inter­molecular N—H⋯S hydrogen bonds. Inter­...

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Detalles Bibliográficos
Autores principales: Fun, Hoong-Kun, Asik, Safra Izuani Jama, Razak, Ibrahim Abdul, Shetty, Shobhitha, Kalluraya, Balakrishna
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247501/
https://www.ncbi.nlm.nih.gov/pubmed/22220119
http://dx.doi.org/10.1107/S1600536811044576
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author Fun, Hoong-Kun
Asik, Safra Izuani Jama
Razak, Ibrahim Abdul
Shetty, Shobhitha
Kalluraya, Balakrishna
author_facet Fun, Hoong-Kun
Asik, Safra Izuani Jama
Razak, Ibrahim Abdul
Shetty, Shobhitha
Kalluraya, Balakrishna
author_sort Fun, Hoong-Kun
collection PubMed
description In the title compound, C(11)H(9)F(2)N(5)OS, the pyrazole ring forms a dihedral angle of 16.42 (6)° with the benzene ring. Intra­molecular N—H⋯O hydrogen bonds generate two S(6) ring motifs. In the crystal, an R (2) (2)(8) ring motif is formed by a pair of inter­molecular N—H⋯S hydrogen bonds. Inter­molecular C—H⋯F hydrogen bonds further link the mol­ecules into a three-dimensional network.
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spelling pubmed-32475012012-01-04 4-[(2,4-Difluoro­phen­yl)hydrazinyl­idene]-3-methyl-5-oxo-4,5-dihydro-1H-pyrazole-1-carbothio­amide Fun, Hoong-Kun Asik, Safra Izuani Jama Razak, Ibrahim Abdul Shetty, Shobhitha Kalluraya, Balakrishna Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(11)H(9)F(2)N(5)OS, the pyrazole ring forms a dihedral angle of 16.42 (6)° with the benzene ring. Intra­molecular N—H⋯O hydrogen bonds generate two S(6) ring motifs. In the crystal, an R (2) (2)(8) ring motif is formed by a pair of inter­molecular N—H⋯S hydrogen bonds. Inter­molecular C—H⋯F hydrogen bonds further link the mol­ecules into a three-dimensional network. International Union of Crystallography 2011-10-29 /pmc/articles/PMC3247501/ /pubmed/22220119 http://dx.doi.org/10.1107/S1600536811044576 Text en © Fun et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Fun, Hoong-Kun
Asik, Safra Izuani Jama
Razak, Ibrahim Abdul
Shetty, Shobhitha
Kalluraya, Balakrishna
4-[(2,4-Difluoro­phen­yl)hydrazinyl­idene]-3-methyl-5-oxo-4,5-dihydro-1H-pyrazole-1-carbothio­amide
title 4-[(2,4-Difluoro­phen­yl)hydrazinyl­idene]-3-methyl-5-oxo-4,5-dihydro-1H-pyrazole-1-carbothio­amide
title_full 4-[(2,4-Difluoro­phen­yl)hydrazinyl­idene]-3-methyl-5-oxo-4,5-dihydro-1H-pyrazole-1-carbothio­amide
title_fullStr 4-[(2,4-Difluoro­phen­yl)hydrazinyl­idene]-3-methyl-5-oxo-4,5-dihydro-1H-pyrazole-1-carbothio­amide
title_full_unstemmed 4-[(2,4-Difluoro­phen­yl)hydrazinyl­idene]-3-methyl-5-oxo-4,5-dihydro-1H-pyrazole-1-carbothio­amide
title_short 4-[(2,4-Difluoro­phen­yl)hydrazinyl­idene]-3-methyl-5-oxo-4,5-dihydro-1H-pyrazole-1-carbothio­amide
title_sort 4-[(2,4-difluoro­phen­yl)hydrazinyl­idene]-3-methyl-5-oxo-4,5-dihydro-1h-pyrazole-1-carbothio­amide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247501/
https://www.ncbi.nlm.nih.gov/pubmed/22220119
http://dx.doi.org/10.1107/S1600536811044576
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