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2,3-Diaminopyridinium 2-hydroxybenzoate
In the title molecular salt, C(5)H(8)N(3) (+)·C(7)H(5)O(3) (−), the 2,3-diaminopyridinium cation is essentially planar, with a maximum deviation of 0.006 (2) Å. In the crystal, adjacent cations and anions are linked by pairs of N—H⋯O hydrogen bonds, generating R (2) (2)(8) loops. These dimers are...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247505/ https://www.ncbi.nlm.nih.gov/pubmed/22220123 http://dx.doi.org/10.1107/S1600536811044461 |
Sumario: | In the title molecular salt, C(5)H(8)N(3) (+)·C(7)H(5)O(3) (−), the 2,3-diaminopyridinium cation is essentially planar, with a maximum deviation of 0.006 (2) Å. In the crystal, adjacent cations and anions are linked by pairs of N—H⋯O hydrogen bonds, generating R (2) (2)(8) loops. These dimers are linked by further N—H⋯O hydrogen bonds and C—H⋯O interactions to form sheets lying parallel to (001). A typical intramolecular O—H⋯O hydrogen bond is also observed in the salicylate (2-hydroxybenzoate) anion, which generates an S(6) ring. The crystal structure also features π–π stacking interactions between the pyridinium rings of the cations, with a centroid–centroid distance of 3.5896 (15) Å. |
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