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2,3-Diamino­pyridinium 2-hy­droxy­benzoate

In the title mol­ecular salt, C(5)H(8)N(3) (+)·C(7)H(5)O(3) (−), the 2,3-diamino­pyridinium cation is essentially planar, with a maximum deviation of 0.006 (2) Å. In the crystal, adjacent cations and anions are linked by pairs of N—H⋯O hydrogen bonds, generating R (2) (2)(8) loops. These dimers are...

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Detalles Bibliográficos
Autores principales: Hemamalini, Madhukar, Goh, Jia Hao, Fun, Hoong-Kun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247505/
https://www.ncbi.nlm.nih.gov/pubmed/22220123
http://dx.doi.org/10.1107/S1600536811044461
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author Hemamalini, Madhukar
Goh, Jia Hao
Fun, Hoong-Kun
author_facet Hemamalini, Madhukar
Goh, Jia Hao
Fun, Hoong-Kun
author_sort Hemamalini, Madhukar
collection PubMed
description In the title mol­ecular salt, C(5)H(8)N(3) (+)·C(7)H(5)O(3) (−), the 2,3-diamino­pyridinium cation is essentially planar, with a maximum deviation of 0.006 (2) Å. In the crystal, adjacent cations and anions are linked by pairs of N—H⋯O hydrogen bonds, generating R (2) (2)(8) loops. These dimers are linked by further N—H⋯O hydrogen bonds and C—H⋯O inter­actions to form sheets lying parallel to (001). A typical intra­molecular O—H⋯O hydrogen bond is also observed in the salicylate (2-hy­droxy­benzoate) anion, which generates an S(6) ring. The crystal structure also features π–π stacking inter­actions between the pyridinium rings of the cations, with a centroid–centroid distance of 3.5896 (15) Å.
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spelling pubmed-32475052012-01-04 2,3-Diamino­pyridinium 2-hy­droxy­benzoate Hemamalini, Madhukar Goh, Jia Hao Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title mol­ecular salt, C(5)H(8)N(3) (+)·C(7)H(5)O(3) (−), the 2,3-diamino­pyridinium cation is essentially planar, with a maximum deviation of 0.006 (2) Å. In the crystal, adjacent cations and anions are linked by pairs of N—H⋯O hydrogen bonds, generating R (2) (2)(8) loops. These dimers are linked by further N—H⋯O hydrogen bonds and C—H⋯O inter­actions to form sheets lying parallel to (001). A typical intra­molecular O—H⋯O hydrogen bond is also observed in the salicylate (2-hy­droxy­benzoate) anion, which generates an S(6) ring. The crystal structure also features π–π stacking inter­actions between the pyridinium rings of the cations, with a centroid–centroid distance of 3.5896 (15) Å. International Union of Crystallography 2011-10-29 /pmc/articles/PMC3247505/ /pubmed/22220123 http://dx.doi.org/10.1107/S1600536811044461 Text en © Hemamalini et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Hemamalini, Madhukar
Goh, Jia Hao
Fun, Hoong-Kun
2,3-Diamino­pyridinium 2-hy­droxy­benzoate
title 2,3-Diamino­pyridinium 2-hy­droxy­benzoate
title_full 2,3-Diamino­pyridinium 2-hy­droxy­benzoate
title_fullStr 2,3-Diamino­pyridinium 2-hy­droxy­benzoate
title_full_unstemmed 2,3-Diamino­pyridinium 2-hy­droxy­benzoate
title_short 2,3-Diamino­pyridinium 2-hy­droxy­benzoate
title_sort 2,3-diamino­pyridinium 2-hy­droxy­benzoate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247505/
https://www.ncbi.nlm.nih.gov/pubmed/22220123
http://dx.doi.org/10.1107/S1600536811044461
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