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2,3-Diaminopyridinium 4-carboxybutanoate
In the title molecular salt, C(5)H(8)N(3) (+)·C(5)H(7)O(4) (−), the 2,3-diaminopyridine molecule is protonated at the pyridine N atom. The cation is essentially planar, with a maximum deviation of 0.015 (2) Å, and the anion adopts an extended conformation. In the crystal, the hydrogen glutarate (...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247507/ https://www.ncbi.nlm.nih.gov/pubmed/22220125 http://dx.doi.org/10.1107/S1600536811044473 |
Sumario: | In the title molecular salt, C(5)H(8)N(3) (+)·C(5)H(7)O(4) (−), the 2,3-diaminopyridine molecule is protonated at the pyridine N atom. The cation is essentially planar, with a maximum deviation of 0.015 (2) Å, and the anion adopts an extended conformation. In the crystal, the hydrogen glutarate (4-carboxybutanoate) anions are self-assembled through O—H⋯O hydrogen bonds, forming chains. The cations are connected to the anion chains via N—H⋯O hydrogen bonds, forming a three-dimensional network. The crystal structure also features aromatic π–π interactions between the pyridinium cations, with a centroid–centroid distance of 3.4464 (10) Å. |
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