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2,3-Diaminopyridinium 4-carboxybutanoate
In the title molecular salt, C(5)H(8)N(3) (+)·C(5)H(7)O(4) (−), the 2,3-diaminopyridine molecule is protonated at the pyridine N atom. The cation is essentially planar, with a maximum deviation of 0.015 (2) Å, and the anion adopts an extended conformation. In the crystal, the hydrogen glutarate (...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247507/ https://www.ncbi.nlm.nih.gov/pubmed/22220125 http://dx.doi.org/10.1107/S1600536811044473 |
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author | Hemamalini, Madhukar Goh, Jia Hao Fun, Hoong-Kun |
author_facet | Hemamalini, Madhukar Goh, Jia Hao Fun, Hoong-Kun |
author_sort | Hemamalini, Madhukar |
collection | PubMed |
description | In the title molecular salt, C(5)H(8)N(3) (+)·C(5)H(7)O(4) (−), the 2,3-diaminopyridine molecule is protonated at the pyridine N atom. The cation is essentially planar, with a maximum deviation of 0.015 (2) Å, and the anion adopts an extended conformation. In the crystal, the hydrogen glutarate (4-carboxybutanoate) anions are self-assembled through O—H⋯O hydrogen bonds, forming chains. The cations are connected to the anion chains via N—H⋯O hydrogen bonds, forming a three-dimensional network. The crystal structure also features aromatic π–π interactions between the pyridinium cations, with a centroid–centroid distance of 3.4464 (10) Å. |
format | Online Article Text |
id | pubmed-3247507 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32475072012-01-04 2,3-Diaminopyridinium 4-carboxybutanoate Hemamalini, Madhukar Goh, Jia Hao Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title molecular salt, C(5)H(8)N(3) (+)·C(5)H(7)O(4) (−), the 2,3-diaminopyridine molecule is protonated at the pyridine N atom. The cation is essentially planar, with a maximum deviation of 0.015 (2) Å, and the anion adopts an extended conformation. In the crystal, the hydrogen glutarate (4-carboxybutanoate) anions are self-assembled through O—H⋯O hydrogen bonds, forming chains. The cations are connected to the anion chains via N—H⋯O hydrogen bonds, forming a three-dimensional network. The crystal structure also features aromatic π–π interactions between the pyridinium cations, with a centroid–centroid distance of 3.4464 (10) Å. International Union of Crystallography 2011-10-29 /pmc/articles/PMC3247507/ /pubmed/22220125 http://dx.doi.org/10.1107/S1600536811044473 Text en © Hemamalini et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Hemamalini, Madhukar Goh, Jia Hao Fun, Hoong-Kun 2,3-Diaminopyridinium 4-carboxybutanoate |
title | 2,3-Diaminopyridinium 4-carboxybutanoate |
title_full | 2,3-Diaminopyridinium 4-carboxybutanoate |
title_fullStr | 2,3-Diaminopyridinium 4-carboxybutanoate |
title_full_unstemmed | 2,3-Diaminopyridinium 4-carboxybutanoate |
title_short | 2,3-Diaminopyridinium 4-carboxybutanoate |
title_sort | 2,3-diaminopyridinium 4-carboxybutanoate |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247507/ https://www.ncbi.nlm.nih.gov/pubmed/22220125 http://dx.doi.org/10.1107/S1600536811044473 |
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