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2,3-Diamino­pyridinium 4-carb­oxy­butano­ate

In the title mol­ecular salt, C(5)H(8)N(3) (+)·C(5)H(7)O(4) (−), the 2,3-diamino­pyridine mol­ecule is protonated at the pyridine N atom. The cation is essentially planar, with a maximum deviation of 0.015 (2) Å, and the anion adopts an extended conformation. In the crystal, the hydrogen glutarate (...

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Detalles Bibliográficos
Autores principales: Hemamalini, Madhukar, Goh, Jia Hao, Fun, Hoong-Kun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247507/
https://www.ncbi.nlm.nih.gov/pubmed/22220125
http://dx.doi.org/10.1107/S1600536811044473
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author Hemamalini, Madhukar
Goh, Jia Hao
Fun, Hoong-Kun
author_facet Hemamalini, Madhukar
Goh, Jia Hao
Fun, Hoong-Kun
author_sort Hemamalini, Madhukar
collection PubMed
description In the title mol­ecular salt, C(5)H(8)N(3) (+)·C(5)H(7)O(4) (−), the 2,3-diamino­pyridine mol­ecule is protonated at the pyridine N atom. The cation is essentially planar, with a maximum deviation of 0.015 (2) Å, and the anion adopts an extended conformation. In the crystal, the hydrogen glutarate (4-carb­oxy­butano­ate) anions are self-assembled through O—H⋯O hydrogen bonds, forming chains. The cations are connected to the anion chains via N—H⋯O hydrogen bonds, forming a three-dimensional network. The crystal structure also features aromatic π–π inter­actions between the pyridinium cations, with a centroid–centroid distance of 3.4464 (10) Å.
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spelling pubmed-32475072012-01-04 2,3-Diamino­pyridinium 4-carb­oxy­butano­ate Hemamalini, Madhukar Goh, Jia Hao Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title mol­ecular salt, C(5)H(8)N(3) (+)·C(5)H(7)O(4) (−), the 2,3-diamino­pyridine mol­ecule is protonated at the pyridine N atom. The cation is essentially planar, with a maximum deviation of 0.015 (2) Å, and the anion adopts an extended conformation. In the crystal, the hydrogen glutarate (4-carb­oxy­butano­ate) anions are self-assembled through O—H⋯O hydrogen bonds, forming chains. The cations are connected to the anion chains via N—H⋯O hydrogen bonds, forming a three-dimensional network. The crystal structure also features aromatic π–π inter­actions between the pyridinium cations, with a centroid–centroid distance of 3.4464 (10) Å. International Union of Crystallography 2011-10-29 /pmc/articles/PMC3247507/ /pubmed/22220125 http://dx.doi.org/10.1107/S1600536811044473 Text en © Hemamalini et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Hemamalini, Madhukar
Goh, Jia Hao
Fun, Hoong-Kun
2,3-Diamino­pyridinium 4-carb­oxy­butano­ate
title 2,3-Diamino­pyridinium 4-carb­oxy­butano­ate
title_full 2,3-Diamino­pyridinium 4-carb­oxy­butano­ate
title_fullStr 2,3-Diamino­pyridinium 4-carb­oxy­butano­ate
title_full_unstemmed 2,3-Diamino­pyridinium 4-carb­oxy­butano­ate
title_short 2,3-Diamino­pyridinium 4-carb­oxy­butano­ate
title_sort 2,3-diamino­pyridinium 4-carb­oxy­butano­ate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247507/
https://www.ncbi.nlm.nih.gov/pubmed/22220125
http://dx.doi.org/10.1107/S1600536811044473
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