N′-(Adamantan-2-yl­idene)thio­phene-2-carbohydrazide

In the title mol­ecule, C(15)H(18)N(2)OS, a small twist is noted, with the dihedral angle between the central carbohydrazone residue (r.m.s. deviation = 0.029 Å) and the thio­phene ring being 12.47 (10)°. The syn arrangement of the amide H and carbonyl O atoms allows for the formation of centrosymme...

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Autores principales: Kadi, Adnan A., Alanzi, Amer M., El-Emam, Ali A., Ng, Seik Weng, Tiekink, Edward R. T.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247511/
https://www.ncbi.nlm.nih.gov/pubmed/22220129
http://dx.doi.org/10.1107/S1600536811044758
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author Kadi, Adnan A.
Alanzi, Amer M.
El-Emam, Ali A.
Ng, Seik Weng
Tiekink, Edward R. T.
author_facet Kadi, Adnan A.
Alanzi, Amer M.
El-Emam, Ali A.
Ng, Seik Weng
Tiekink, Edward R. T.
author_sort Kadi, Adnan A.
collection PubMed
description In the title mol­ecule, C(15)H(18)N(2)OS, a small twist is noted, with the dihedral angle between the central carbohydrazone residue (r.m.s. deviation = 0.029 Å) and the thio­phene ring being 12.47 (10)°. The syn arrangement of the amide H and carbonyl O atoms allows for the formation of centrosymmetric dimers via N—H⋯O hydrogen bonds. These are linked in the three-dimensional structure by C—H⋯π inter­actions. The thio­phene ring is disordered over two co-planar orientations, the major component having a site-occupancy factor of 0.833 (2).
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spelling pubmed-32475112012-01-04 N′-(Adamantan-2-yl­idene)thio­phene-2-carbohydrazide Kadi, Adnan A. Alanzi, Amer M. El-Emam, Ali A. Ng, Seik Weng Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title mol­ecule, C(15)H(18)N(2)OS, a small twist is noted, with the dihedral angle between the central carbohydrazone residue (r.m.s. deviation = 0.029 Å) and the thio­phene ring being 12.47 (10)°. The syn arrangement of the amide H and carbonyl O atoms allows for the formation of centrosymmetric dimers via N—H⋯O hydrogen bonds. These are linked in the three-dimensional structure by C—H⋯π inter­actions. The thio­phene ring is disordered over two co-planar orientations, the major component having a site-occupancy factor of 0.833 (2). International Union of Crystallography 2011-10-29 /pmc/articles/PMC3247511/ /pubmed/22220129 http://dx.doi.org/10.1107/S1600536811044758 Text en © Kadi et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Kadi, Adnan A.
Alanzi, Amer M.
El-Emam, Ali A.
Ng, Seik Weng
Tiekink, Edward R. T.
N′-(Adamantan-2-yl­idene)thio­phene-2-carbohydrazide
title N′-(Adamantan-2-yl­idene)thio­phene-2-carbohydrazide
title_full N′-(Adamantan-2-yl­idene)thio­phene-2-carbohydrazide
title_fullStr N′-(Adamantan-2-yl­idene)thio­phene-2-carbohydrazide
title_full_unstemmed N′-(Adamantan-2-yl­idene)thio­phene-2-carbohydrazide
title_short N′-(Adamantan-2-yl­idene)thio­phene-2-carbohydrazide
title_sort n′-(adamantan-2-yl­idene)thio­phene-2-carbohydrazide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247511/
https://www.ncbi.nlm.nih.gov/pubmed/22220129
http://dx.doi.org/10.1107/S1600536811044758
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