fac-Tris(pyridine-2-carboxyl­ato-κ(2) N,O)cobalt(III)

In the title compound, [Co(C(6)H(4)NO(2))(3)], the Co(III) ion lies on a threefold rotation axis and is in a distorted octa­hedral environment defined by three N and three O donor atoms from three fac-disposed pyridine-2-carboxyl­ate ligands. The ligands are coordinated in a chelate fashion, forming...

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Autores principales: Golenia, Irina A., Boyko, Alexander N., Kotova, Natalia V., Haukka, Matti, Kalibabchuk, Valentina A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247521/
https://www.ncbi.nlm.nih.gov/pubmed/22219826
http://dx.doi.org/10.1107/S1600536811043303
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author Golenia, Irina A.
Boyko, Alexander N.
Kotova, Natalia V.
Haukka, Matti
Kalibabchuk, Valentina A.
author_facet Golenia, Irina A.
Boyko, Alexander N.
Kotova, Natalia V.
Haukka, Matti
Kalibabchuk, Valentina A.
author_sort Golenia, Irina A.
collection PubMed
description In the title compound, [Co(C(6)H(4)NO(2))(3)], the Co(III) ion lies on a threefold rotation axis and is in a distorted octa­hedral environment defined by three N and three O donor atoms from three fac-disposed pyridine-2-carboxyl­ate ligands. The ligands are coordinated in a chelate fashion, forming three five-membered rings. In the crystal, translationally related complex molecules are organized into columns along [001] via C—H⋯O hydrogen bonds.
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spelling pubmed-32475212012-01-04 fac-Tris(pyridine-2-carboxyl­ato-κ(2) N,O)cobalt(III) Golenia, Irina A. Boyko, Alexander N. Kotova, Natalia V. Haukka, Matti Kalibabchuk, Valentina A. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Co(C(6)H(4)NO(2))(3)], the Co(III) ion lies on a threefold rotation axis and is in a distorted octa­hedral environment defined by three N and three O donor atoms from three fac-disposed pyridine-2-carboxyl­ate ligands. The ligands are coordinated in a chelate fashion, forming three five-membered rings. In the crystal, translationally related complex molecules are organized into columns along [001] via C—H⋯O hydrogen bonds. International Union of Crystallography 2011-10-29 /pmc/articles/PMC3247521/ /pubmed/22219826 http://dx.doi.org/10.1107/S1600536811043303 Text en © Golenia et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Golenia, Irina A.
Boyko, Alexander N.
Kotova, Natalia V.
Haukka, Matti
Kalibabchuk, Valentina A.
fac-Tris(pyridine-2-carboxyl­ato-κ(2) N,O)cobalt(III)
title fac-Tris(pyridine-2-carboxyl­ato-κ(2) N,O)cobalt(III)
title_full fac-Tris(pyridine-2-carboxyl­ato-κ(2) N,O)cobalt(III)
title_fullStr fac-Tris(pyridine-2-carboxyl­ato-κ(2) N,O)cobalt(III)
title_full_unstemmed fac-Tris(pyridine-2-carboxyl­ato-κ(2) N,O)cobalt(III)
title_short fac-Tris(pyridine-2-carboxyl­ato-κ(2) N,O)cobalt(III)
title_sort fac-tris(pyridine-2-carboxyl­ato-κ(2) n,o)cobalt(iii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247521/
https://www.ncbi.nlm.nih.gov/pubmed/22219826
http://dx.doi.org/10.1107/S1600536811043303
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