Bis{μ-2-[1-(pyridin-2-yl­methyl­imino)­eth­yl]phenolato}bis­(azido­zinc)

The title compound, [Zn(2)(C(14)H(13)N(2)O)(2)(N(3))(2)], is a phenolate-bridged centrosymmetric dinuclear zinc(II) complex. The Zn⋯Zn distance is 3.076 (1) Å. Each Zn atom is five-coordinated by two O and two N atoms from two Schiff base ligands, and by one azide N atom, forming a square-pyramidal...

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Detalles Bibliográficos
Autor principal: Miao, Jian-Ying
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247522/
https://www.ncbi.nlm.nih.gov/pubmed/22219827
http://dx.doi.org/10.1107/S1600536811043455
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author Miao, Jian-Ying
author_facet Miao, Jian-Ying
author_sort Miao, Jian-Ying
collection PubMed
description The title compound, [Zn(2)(C(14)H(13)N(2)O)(2)(N(3))(2)], is a phenolate-bridged centrosymmetric dinuclear zinc(II) complex. The Zn⋯Zn distance is 3.076 (1) Å. Each Zn atom is five-coordinated by two O and two N atoms from two Schiff base ligands, and by one azide N atom, forming a square-pyramidal geometry.
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spelling pubmed-32475222012-01-04 Bis{μ-2-[1-(pyridin-2-yl­methyl­imino)­eth­yl]phenolato}bis­(azido­zinc) Miao, Jian-Ying Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Zn(2)(C(14)H(13)N(2)O)(2)(N(3))(2)], is a phenolate-bridged centrosymmetric dinuclear zinc(II) complex. The Zn⋯Zn distance is 3.076 (1) Å. Each Zn atom is five-coordinated by two O and two N atoms from two Schiff base ligands, and by one azide N atom, forming a square-pyramidal geometry. International Union of Crystallography 2011-10-29 /pmc/articles/PMC3247522/ /pubmed/22219827 http://dx.doi.org/10.1107/S1600536811043455 Text en © Jian-Ying Miao 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Miao, Jian-Ying
Bis{μ-2-[1-(pyridin-2-yl­methyl­imino)­eth­yl]phenolato}bis­(azido­zinc)
title Bis{μ-2-[1-(pyridin-2-yl­methyl­imino)­eth­yl]phenolato}bis­(azido­zinc)
title_full Bis{μ-2-[1-(pyridin-2-yl­methyl­imino)­eth­yl]phenolato}bis­(azido­zinc)
title_fullStr Bis{μ-2-[1-(pyridin-2-yl­methyl­imino)­eth­yl]phenolato}bis­(azido­zinc)
title_full_unstemmed Bis{μ-2-[1-(pyridin-2-yl­methyl­imino)­eth­yl]phenolato}bis­(azido­zinc)
title_short Bis{μ-2-[1-(pyridin-2-yl­methyl­imino)­eth­yl]phenolato}bis­(azido­zinc)
title_sort bis{μ-2-[1-(pyridin-2-yl­methyl­imino)­eth­yl]phenolato}bis­(azido­zinc)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247522/
https://www.ncbi.nlm.nih.gov/pubmed/22219827
http://dx.doi.org/10.1107/S1600536811043455
work_keys_str_mv AT miaojianying bism21pyridin2ylmethyliminoethylphenolatobisazidozinc

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