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Tris(2-amino­pyridinium) hexa­chlorido­indate(III)

The Schiff base (E)-4-chloro-2-[(pyridin-2-yl­imino)­meth­yl]phenol was reacted with InCl(3)·4H(2)O, generating the title molecular salt, (C(5)H(7)N(2))(3)[InCl(6)]. The octa­hedral hexa­chlorido­indate(III) anion is located on an inversion centre, and one half of the anion and two crystallographica...

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Autores principales: Jin, Xu-Dong, Sun, Li-Cai, Wang, Hai-Bo, Ge, Chun-Hua
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247525/
https://www.ncbi.nlm.nih.gov/pubmed/22219830
http://dx.doi.org/10.1107/S1600536811043285
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author Jin, Xu-Dong
Sun, Li-Cai
Wang, Hai-Bo
Ge, Chun-Hua
author_facet Jin, Xu-Dong
Sun, Li-Cai
Wang, Hai-Bo
Ge, Chun-Hua
author_sort Jin, Xu-Dong
collection PubMed
description The Schiff base (E)-4-chloro-2-[(pyridin-2-yl­imino)­meth­yl]phenol was reacted with InCl(3)·4H(2)O, generating the title molecular salt, (C(5)H(7)N(2))(3)[InCl(6)]. The octa­hedral hexa­chlorido­indate(III) anion is located on an inversion centre, and one half of the anion and two crystallographically independent cations form the asymmetric unit. One of the cations is located on a twofold rotation axis and its intra-ring C and N atoms simulate this symmetry by exchanging their positions in statistical disorder. In the crystal, weak N—H⋯Cl hydrogen bonds and two types of π–π interactions with centroid–centroid separations of 4.047 (3) and 4.202 (3) Å are observed.
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spelling pubmed-32475252012-01-04 Tris(2-amino­pyridinium) hexa­chlorido­indate(III) Jin, Xu-Dong Sun, Li-Cai Wang, Hai-Bo Ge, Chun-Hua Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The Schiff base (E)-4-chloro-2-[(pyridin-2-yl­imino)­meth­yl]phenol was reacted with InCl(3)·4H(2)O, generating the title molecular salt, (C(5)H(7)N(2))(3)[InCl(6)]. The octa­hedral hexa­chlorido­indate(III) anion is located on an inversion centre, and one half of the anion and two crystallographically independent cations form the asymmetric unit. One of the cations is located on a twofold rotation axis and its intra-ring C and N atoms simulate this symmetry by exchanging their positions in statistical disorder. In the crystal, weak N—H⋯Cl hydrogen bonds and two types of π–π interactions with centroid–centroid separations of 4.047 (3) and 4.202 (3) Å are observed. International Union of Crystallography 2011-10-29 /pmc/articles/PMC3247525/ /pubmed/22219830 http://dx.doi.org/10.1107/S1600536811043285 Text en © Jin et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Jin, Xu-Dong
Sun, Li-Cai
Wang, Hai-Bo
Ge, Chun-Hua
Tris(2-amino­pyridinium) hexa­chlorido­indate(III)
title Tris(2-amino­pyridinium) hexa­chlorido­indate(III)
title_full Tris(2-amino­pyridinium) hexa­chlorido­indate(III)
title_fullStr Tris(2-amino­pyridinium) hexa­chlorido­indate(III)
title_full_unstemmed Tris(2-amino­pyridinium) hexa­chlorido­indate(III)
title_short Tris(2-amino­pyridinium) hexa­chlorido­indate(III)
title_sort tris(2-amino­pyridinium) hexa­chlorido­indate(iii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247525/
https://www.ncbi.nlm.nih.gov/pubmed/22219830
http://dx.doi.org/10.1107/S1600536811043285
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