trans-Bis(thio­cyanato-κN)tetra­kis­(3,4,5-trimethyl-1H-pyrazole-κN (2))nickel(II)–3,4,5-trimethyl-1H-pyrazole (1/1)

In the title compound, [Ni(NCS)(2)(C(6)H(10)N(2))(4)]·C(6)H(10)N(2), the asymmetric unit comprises a Ni(II) complex and a co-crystallised mol­ecule of 3,4,5-trimethyl-1H-pyrazole (PzMe(3)). The Ni(II) atom is coordinated by four PzMe(3) mol­ecules and two thio­cyanate anions to define a trans N(4)S(...

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Detalles Bibliográficos
Autores principales: Hossaini Sadr, Moayad, Engle, James T., Ziegler, Christopher J., Soltani, Behzad, Mousavi, Zahra
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247526/
https://www.ncbi.nlm.nih.gov/pubmed/22219831
http://dx.doi.org/10.1107/S1600536811041419
Descripción
Sumario:In the title compound, [Ni(NCS)(2)(C(6)H(10)N(2))(4)]·C(6)H(10)N(2), the asymmetric unit comprises a Ni(II) complex and a co-crystallised mol­ecule of 3,4,5-trimethyl-1H-pyrazole (PzMe(3)). The Ni(II) atom is coordinated by four PzMe(3) mol­ecules and two thio­cyanate anions to define a trans N(4)S(2) distorted octa­hedral geometry. A number of intra­molecular N—H⋯N, N—H⋯S and C—H⋯N inter­actions contribute to the stability of the complex. The crystal structure is stabilized by inter­molecular N—H⋯S inter­actions, which link neighbouring mol­ecules into chains along the a axis.

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