Bis{1-[4-(benz­yloxy)phen­yl]-4,4,4-tri­fluoro­butane-1,3-dionato(1−)}dipyri­dine­cobalt(II)

In the title compound, [Co(C(17)H(12)F(3)O(3))(2)(C(5)H(5)N)(2)], the Co(II) ion is situated on a twofold rotation axis, coordinated by four O atoms from two 1-[4-(benz­yloxy)phen­yl]-4,4,4-trifluoro­butane-1,3-dionate(1−) (L) ligands and two N atoms from two pyridine ligands in a distorted octa­hed...

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Detalles Bibliográficos
Autores principales: Fan, Ling, Chen, Yongzhou, Wei, Xianhong, Yin, Guodong
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247528/
https://www.ncbi.nlm.nih.gov/pubmed/22219833
http://dx.doi.org/10.1107/S1600536811043157
Descripción
Sumario:In the title compound, [Co(C(17)H(12)F(3)O(3))(2)(C(5)H(5)N)(2)], the Co(II) ion is situated on a twofold rotation axis, coordinated by four O atoms from two 1-[4-(benz­yloxy)phen­yl]-4,4,4-trifluoro­butane-1,3-dionate(1−) (L) ligands and two N atoms from two pyridine ligands in a distorted octa­hedral geometry. The two pyridine rings form a dihedral angle of 84.63 (7)°. The two benzene rings in L are twisted at 58.83 (5)°. Weak inter­molecular C—H⋯F hydrogen bonds consolidate the crystal packing.

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