Bis{1-[4-(benz­yloxy)phen­yl]-4,4,4-tri­fluoro­butane-1,3-dionato(1−)}dipyri­dine­cobalt(II)

In the title compound, [Co(C(17)H(12)F(3)O(3))(2)(C(5)H(5)N)(2)], the Co(II) ion is situated on a twofold rotation axis, coordinated by four O atoms from two 1-[4-(benz­yloxy)phen­yl]-4,4,4-trifluoro­butane-1,3-dionate(1−) (L) ligands and two N atoms from two pyridine ligands in a distorted octa­hed...

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Detalles Bibliográficos
Autores principales: Fan, Ling, Chen, Yongzhou, Wei, Xianhong, Yin, Guodong
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247528/
https://www.ncbi.nlm.nih.gov/pubmed/22219833
http://dx.doi.org/10.1107/S1600536811043157
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author Fan, Ling
Chen, Yongzhou
Wei, Xianhong
Yin, Guodong
author_facet Fan, Ling
Chen, Yongzhou
Wei, Xianhong
Yin, Guodong
author_sort Fan, Ling
collection PubMed
description In the title compound, [Co(C(17)H(12)F(3)O(3))(2)(C(5)H(5)N)(2)], the Co(II) ion is situated on a twofold rotation axis, coordinated by four O atoms from two 1-[4-(benz­yloxy)phen­yl]-4,4,4-trifluoro­butane-1,3-dionate(1−) (L) ligands and two N atoms from two pyridine ligands in a distorted octa­hedral geometry. The two pyridine rings form a dihedral angle of 84.63 (7)°. The two benzene rings in L are twisted at 58.83 (5)°. Weak inter­molecular C—H⋯F hydrogen bonds consolidate the crystal packing.
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spelling pubmed-32475282012-01-04 Bis{1-[4-(benz­yloxy)phen­yl]-4,4,4-tri­fluoro­butane-1,3-dionato(1−)}dipyri­dine­cobalt(II) Fan, Ling Chen, Yongzhou Wei, Xianhong Yin, Guodong Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Co(C(17)H(12)F(3)O(3))(2)(C(5)H(5)N)(2)], the Co(II) ion is situated on a twofold rotation axis, coordinated by four O atoms from two 1-[4-(benz­yloxy)phen­yl]-4,4,4-trifluoro­butane-1,3-dionate(1−) (L) ligands and two N atoms from two pyridine ligands in a distorted octa­hedral geometry. The two pyridine rings form a dihedral angle of 84.63 (7)°. The two benzene rings in L are twisted at 58.83 (5)°. Weak inter­molecular C—H⋯F hydrogen bonds consolidate the crystal packing. International Union of Crystallography 2011-10-29 /pmc/articles/PMC3247528/ /pubmed/22219833 http://dx.doi.org/10.1107/S1600536811043157 Text en © Fan et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Fan, Ling
Chen, Yongzhou
Wei, Xianhong
Yin, Guodong
Bis{1-[4-(benz­yloxy)phen­yl]-4,4,4-tri­fluoro­butane-1,3-dionato(1−)}dipyri­dine­cobalt(II)
title Bis{1-[4-(benz­yloxy)phen­yl]-4,4,4-tri­fluoro­butane-1,3-dionato(1−)}dipyri­dine­cobalt(II)
title_full Bis{1-[4-(benz­yloxy)phen­yl]-4,4,4-tri­fluoro­butane-1,3-dionato(1−)}dipyri­dine­cobalt(II)
title_fullStr Bis{1-[4-(benz­yloxy)phen­yl]-4,4,4-tri­fluoro­butane-1,3-dionato(1−)}dipyri­dine­cobalt(II)
title_full_unstemmed Bis{1-[4-(benz­yloxy)phen­yl]-4,4,4-tri­fluoro­butane-1,3-dionato(1−)}dipyri­dine­cobalt(II)
title_short Bis{1-[4-(benz­yloxy)phen­yl]-4,4,4-tri­fluoro­butane-1,3-dionato(1−)}dipyri­dine­cobalt(II)
title_sort bis{1-[4-(benz­yloxy)phen­yl]-4,4,4-tri­fluoro­butane-1,3-dionato(1−)}dipyri­dine­cobalt(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247528/
https://www.ncbi.nlm.nih.gov/pubmed/22219833
http://dx.doi.org/10.1107/S1600536811043157
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