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1-(4-Iodo­benz­yl)-3-methyl­pyridinium bis­(benzene-1,2-dithiol­ato)nickelate(III)

The asymmetric unit of the title compound, (C(13)H(13)IN)[Ni(C(6)H(4)S(2))(2)], contains half each of two centrosymmetric anions and a single cation in a general position. In the anions, the Ni(III) ions are surrounded by four S atoms in a distorted square-planar geometry. In the crystal, the anions...

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Detalles Bibliográficos
Autor principal: Liu, Guang-Xiang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247529/
https://www.ncbi.nlm.nih.gov/pubmed/22219834
http://dx.doi.org/10.1107/S1600536811043522
Descripción
Sumario:The asymmetric unit of the title compound, (C(13)H(13)IN)[Ni(C(6)H(4)S(2))(2)], contains half each of two centrosymmetric anions and a single cation in a general position. In the anions, the Ni(III) ions are surrounded by four S atoms in a distorted square-planar geometry. In the crystal, the anions exhibit two different packing modes by stacking along the a axis in face-to-face and side-by-side fashions. Inter­ionic C—H⋯S hydrogen bonds and π–π stacking inter­actions [centroid–centroid distance = 3.6947 (5) Å] are observed.