1-(4-Iodo­benz­yl)-3-methyl­pyridinium bis­(benzene-1,2-dithiol­ato)nickelate(III)

The asymmetric unit of the title compound, (C(13)H(13)IN)[Ni(C(6)H(4)S(2))(2)], contains half each of two centrosymmetric anions and a single cation in a general position. In the anions, the Ni(III) ions are surrounded by four S atoms in a distorted square-planar geometry. In the crystal, the anions...

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Autor principal: Liu, Guang-Xiang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247529/
https://www.ncbi.nlm.nih.gov/pubmed/22219834
http://dx.doi.org/10.1107/S1600536811043522
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author Liu, Guang-Xiang
author_facet Liu, Guang-Xiang
author_sort Liu, Guang-Xiang
collection PubMed
description The asymmetric unit of the title compound, (C(13)H(13)IN)[Ni(C(6)H(4)S(2))(2)], contains half each of two centrosymmetric anions and a single cation in a general position. In the anions, the Ni(III) ions are surrounded by four S atoms in a distorted square-planar geometry. In the crystal, the anions exhibit two different packing modes by stacking along the a axis in face-to-face and side-by-side fashions. Inter­ionic C—H⋯S hydrogen bonds and π–π stacking inter­actions [centroid–centroid distance = 3.6947 (5) Å] are observed.
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spelling pubmed-32475292012-01-04 1-(4-Iodo­benz­yl)-3-methyl­pyridinium bis­(benzene-1,2-dithiol­ato)nickelate(III) Liu, Guang-Xiang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, (C(13)H(13)IN)[Ni(C(6)H(4)S(2))(2)], contains half each of two centrosymmetric anions and a single cation in a general position. In the anions, the Ni(III) ions are surrounded by four S atoms in a distorted square-planar geometry. In the crystal, the anions exhibit two different packing modes by stacking along the a axis in face-to-face and side-by-side fashions. Inter­ionic C—H⋯S hydrogen bonds and π–π stacking inter­actions [centroid–centroid distance = 3.6947 (5) Å] are observed. International Union of Crystallography 2011-10-29 /pmc/articles/PMC3247529/ /pubmed/22219834 http://dx.doi.org/10.1107/S1600536811043522 Text en © Guang-Xiang Liu 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Liu, Guang-Xiang
1-(4-Iodo­benz­yl)-3-methyl­pyridinium bis­(benzene-1,2-dithiol­ato)nickelate(III)
title 1-(4-Iodo­benz­yl)-3-methyl­pyridinium bis­(benzene-1,2-dithiol­ato)nickelate(III)
title_full 1-(4-Iodo­benz­yl)-3-methyl­pyridinium bis­(benzene-1,2-dithiol­ato)nickelate(III)
title_fullStr 1-(4-Iodo­benz­yl)-3-methyl­pyridinium bis­(benzene-1,2-dithiol­ato)nickelate(III)
title_full_unstemmed 1-(4-Iodo­benz­yl)-3-methyl­pyridinium bis­(benzene-1,2-dithiol­ato)nickelate(III)
title_short 1-(4-Iodo­benz­yl)-3-methyl­pyridinium bis­(benzene-1,2-dithiol­ato)nickelate(III)
title_sort 1-(4-iodo­benz­yl)-3-methyl­pyridinium bis­(benzene-1,2-dithiol­ato)nickelate(iii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247529/
https://www.ncbi.nlm.nih.gov/pubmed/22219834
http://dx.doi.org/10.1107/S1600536811043522
work_keys_str_mv AT liuguangxiang 14iodobenzyl3methylpyridiniumbisbenzene12dithiolatonickelateiii

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