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Diaquabis(1,10-phenanthroline-κ(2) N,N′)cadmium sulfate hexahydrate
The title compound, [Cd(C(12)H(8)N(2))(2)(H(2)O)(2)]SO(4)·6H(2)O, was obtained unexpectedly during an attempt to synthesize a cadmium complex with bidentate bridging sulfate ligands via hydrothermal synthesis. The Cd(II) metal ion is six-coordinated by two chelating 1,10-phenanthroline ligands and...
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247531/ https://www.ncbi.nlm.nih.gov/pubmed/22219836 http://dx.doi.org/10.1107/S1600536811043194 |
Sumario: | The title compound, [Cd(C(12)H(8)N(2))(2)(H(2)O)(2)]SO(4)·6H(2)O, was obtained unexpectedly during an attempt to synthesize a cadmium complex with bidentate bridging sulfate ligands via hydrothermal synthesis. The Cd(II) metal ion is six-coordinated by two chelating 1,10-phenanthroline ligands and two water molecules, resulting in a distorted octahedral geometry for the metal ion. The two chelating N(2)C(2) groups are almost perpendicular to each other [dihedral angle = 86.75 (2)°]. In the crystal, the [Cd(C(12)H(8)N(2))(2)(H(2)O)(2)](2+) complex cations join with the sulfate anions through two O(water)—H⋯O(sulfate) hydrogen bonds. These ion pairs are further interlinked into a two-dimensional supermolecular structure via additional O—H⋯O hydrogen bonds. |
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