Dichlorido[1-(2-chloro­eth­yl)-3-(pyridin-4-ylmethyl-κN)urea](η(6)-hexa­methyl­benzene)­ruthenium(II) chloro­form monosolvate

The Ru(II) atom in the title compound, [RuCl(2)(C(12)H(18))(C(9)H(12)ClN(3)O)]·CHCl(3), exhibits a typical piano-stool coordination, defined by a hexa­methyl­benzene ligand, two chloride ligands and a pyridyl­urea ligand coordinated through the pyridine N atom. In the crystal, a dimeric structure is...

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Detalles Bibliográficos
Autores principales: Auzias, Mathieu, Süss-Fink, Georg, Therrien, Bruno
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247534/
https://www.ncbi.nlm.nih.gov/pubmed/22219839
http://dx.doi.org/10.1107/S1600536811043728
Descripción
Sumario:The Ru(II) atom in the title compound, [RuCl(2)(C(12)H(18))(C(9)H(12)ClN(3)O)]·CHCl(3), exhibits a typical piano-stool coordination, defined by a hexa­methyl­benzene ligand, two chloride ligands and a pyridyl­urea ligand coordinated through the pyridine N atom. In the crystal, a dimeric structure is observed due to two strong N—H⋯Cl inter­actions between the NH groups of urea and the two chloride ligands of neighbouring mol­ecules. In addition, the C=O group of the urea moiety inter­acts with the solvent mol­ecule through weak C—H⋯O interactions.

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