Dichlorido[1-(2-chloro­eth­yl)-3-(pyridin-4-ylmethyl-κN)urea](η(6)-hexa­methyl­benzene)­ruthenium(II) chloro­form monosolvate

The Ru(II) atom in the title compound, [RuCl(2)(C(12)H(18))(C(9)H(12)ClN(3)O)]·CHCl(3), exhibits a typical piano-stool coordination, defined by a hexa­methyl­benzene ligand, two chloride ligands and a pyridyl­urea ligand coordinated through the pyridine N atom. In the crystal, a dimeric structure is...

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Detalles Bibliográficos
Autores principales: Auzias, Mathieu, Süss-Fink, Georg, Therrien, Bruno
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247534/
https://www.ncbi.nlm.nih.gov/pubmed/22219839
http://dx.doi.org/10.1107/S1600536811043728
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author Auzias, Mathieu
Süss-Fink, Georg
Therrien, Bruno
author_facet Auzias, Mathieu
Süss-Fink, Georg
Therrien, Bruno
author_sort Auzias, Mathieu
collection PubMed
description The Ru(II) atom in the title compound, [RuCl(2)(C(12)H(18))(C(9)H(12)ClN(3)O)]·CHCl(3), exhibits a typical piano-stool coordination, defined by a hexa­methyl­benzene ligand, two chloride ligands and a pyridyl­urea ligand coordinated through the pyridine N atom. In the crystal, a dimeric structure is observed due to two strong N—H⋯Cl inter­actions between the NH groups of urea and the two chloride ligands of neighbouring mol­ecules. In addition, the C=O group of the urea moiety inter­acts with the solvent mol­ecule through weak C—H⋯O interactions.
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spelling pubmed-32475342012-01-04 Dichlorido[1-(2-chloro­eth­yl)-3-(pyridin-4-ylmethyl-κN)urea](η(6)-hexa­methyl­benzene)­ruthenium(II) chloro­form monosolvate Auzias, Mathieu Süss-Fink, Georg Therrien, Bruno Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The Ru(II) atom in the title compound, [RuCl(2)(C(12)H(18))(C(9)H(12)ClN(3)O)]·CHCl(3), exhibits a typical piano-stool coordination, defined by a hexa­methyl­benzene ligand, two chloride ligands and a pyridyl­urea ligand coordinated through the pyridine N atom. In the crystal, a dimeric structure is observed due to two strong N—H⋯Cl inter­actions between the NH groups of urea and the two chloride ligands of neighbouring mol­ecules. In addition, the C=O group of the urea moiety inter­acts with the solvent mol­ecule through weak C—H⋯O interactions. International Union of Crystallography 2011-10-29 /pmc/articles/PMC3247534/ /pubmed/22219839 http://dx.doi.org/10.1107/S1600536811043728 Text en © Auzias et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Auzias, Mathieu
Süss-Fink, Georg
Therrien, Bruno
Dichlorido[1-(2-chloro­eth­yl)-3-(pyridin-4-ylmethyl-κN)urea](η(6)-hexa­methyl­benzene)­ruthenium(II) chloro­form monosolvate
title Dichlorido[1-(2-chloro­eth­yl)-3-(pyridin-4-ylmethyl-κN)urea](η(6)-hexa­methyl­benzene)­ruthenium(II) chloro­form monosolvate
title_full Dichlorido[1-(2-chloro­eth­yl)-3-(pyridin-4-ylmethyl-κN)urea](η(6)-hexa­methyl­benzene)­ruthenium(II) chloro­form monosolvate
title_fullStr Dichlorido[1-(2-chloro­eth­yl)-3-(pyridin-4-ylmethyl-κN)urea](η(6)-hexa­methyl­benzene)­ruthenium(II) chloro­form monosolvate
title_full_unstemmed Dichlorido[1-(2-chloro­eth­yl)-3-(pyridin-4-ylmethyl-κN)urea](η(6)-hexa­methyl­benzene)­ruthenium(II) chloro­form monosolvate
title_short Dichlorido[1-(2-chloro­eth­yl)-3-(pyridin-4-ylmethyl-κN)urea](η(6)-hexa­methyl­benzene)­ruthenium(II) chloro­form monosolvate
title_sort dichlorido[1-(2-chloro­eth­yl)-3-(pyridin-4-ylmethyl-κn)urea](η(6)-hexa­methyl­benzene)­ruthenium(ii) chloro­form monosolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247534/
https://www.ncbi.nlm.nih.gov/pubmed/22219839
http://dx.doi.org/10.1107/S1600536811043728
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AT sussfinkgeorg dichlorido12chloroethyl3pyridin4ylmethylknureaē6hexamethylbenzenerutheniumiichloroformmonosolvate
AT therrienbruno dichlorido12chloroethyl3pyridin4ylmethylknureaē6hexamethylbenzenerutheniumiichloroformmonosolvate

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