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Dichlorido(2,3-di-2-pyridyl­pyrazine-κ(2) N (2),N (3))palladium(II)

The Pd(II) ion in the title complex, [PdCl(2)(C(14)H(10)N(4))], has a slightly distorted square-planar environment defined by the two pyridine N atoms of the chelating 2,3-di-2-pyridyl­pyrazine ligand and two chloride anions. The pyridine rings are considerably inclined to the least-squares plane of...

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Detalles Bibliográficos
Autor principal: Ha, Kwang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247536/
https://www.ncbi.nlm.nih.gov/pubmed/22219841
http://dx.doi.org/10.1107/S1600536811043753
Descripción
Sumario:The Pd(II) ion in the title complex, [PdCl(2)(C(14)H(10)N(4))], has a slightly distorted square-planar environment defined by the two pyridine N atoms of the chelating 2,3-di-2-pyridyl­pyrazine ligand and two chloride anions. The pyridine rings are considerably inclined to the least-squares plane of the PdCl(2)N(2) unit [maximum deviation = 0.073 (1) Å], with dihedral angles of 64.19 (9) and 66.55 (9)°. The pyrazine ring is almost perpendicular to this plane and the dihedral angle is 88.2 (1)°. Two independent inter­molecular C—H⋯Cl hydrogen bonds, both involving the same Cl atom as a hydrogen-bond acceptor, give rise to chains running along the a and b axes, generating a layer structure extending parallel to (001). Mol­ecules are stacked in columns along the a axis. Along the b axis, successive mol­ecules stack in opposite directions.