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Dichlorido(2,3-di-2-pyridylpyrazine-κ(2) N (2),N (3))palladium(II)
The Pd(II) ion in the title complex, [PdCl(2)(C(14)H(10)N(4))], has a slightly distorted square-planar environment defined by the two pyridine N atoms of the chelating 2,3-di-2-pyridylpyrazine ligand and two chloride anions. The pyridine rings are considerably inclined to the least-squares plane of...
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Formato: | Online Artículo Texto |
Lenguaje: | English |
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International Union of Crystallography
2011
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247536/ https://www.ncbi.nlm.nih.gov/pubmed/22219841 http://dx.doi.org/10.1107/S1600536811043753 |
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author | Ha, Kwang |
author_facet | Ha, Kwang |
author_sort | Ha, Kwang |
collection | PubMed |
description | The Pd(II) ion in the title complex, [PdCl(2)(C(14)H(10)N(4))], has a slightly distorted square-planar environment defined by the two pyridine N atoms of the chelating 2,3-di-2-pyridylpyrazine ligand and two chloride anions. The pyridine rings are considerably inclined to the least-squares plane of the PdCl(2)N(2) unit [maximum deviation = 0.073 (1) Å], with dihedral angles of 64.19 (9) and 66.55 (9)°. The pyrazine ring is almost perpendicular to this plane and the dihedral angle is 88.2 (1)°. Two independent intermolecular C—H⋯Cl hydrogen bonds, both involving the same Cl atom as a hydrogen-bond acceptor, give rise to chains running along the a and b axes, generating a layer structure extending parallel to (001). Molecules are stacked in columns along the a axis. Along the b axis, successive molecules stack in opposite directions. |
format | Online Article Text |
id | pubmed-3247536 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32475362012-01-04 Dichlorido(2,3-di-2-pyridylpyrazine-κ(2) N (2),N (3))palladium(II) Ha, Kwang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The Pd(II) ion in the title complex, [PdCl(2)(C(14)H(10)N(4))], has a slightly distorted square-planar environment defined by the two pyridine N atoms of the chelating 2,3-di-2-pyridylpyrazine ligand and two chloride anions. The pyridine rings are considerably inclined to the least-squares plane of the PdCl(2)N(2) unit [maximum deviation = 0.073 (1) Å], with dihedral angles of 64.19 (9) and 66.55 (9)°. The pyrazine ring is almost perpendicular to this plane and the dihedral angle is 88.2 (1)°. Two independent intermolecular C—H⋯Cl hydrogen bonds, both involving the same Cl atom as a hydrogen-bond acceptor, give rise to chains running along the a and b axes, generating a layer structure extending parallel to (001). Molecules are stacked in columns along the a axis. Along the b axis, successive molecules stack in opposite directions. International Union of Crystallography 2011-10-29 /pmc/articles/PMC3247536/ /pubmed/22219841 http://dx.doi.org/10.1107/S1600536811043753 Text en © Kwang Ha 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Ha, Kwang Dichlorido(2,3-di-2-pyridylpyrazine-κ(2) N (2),N (3))palladium(II) |
title | Dichlorido(2,3-di-2-pyridylpyrazine-κ(2)
N
(2),N
(3))palladium(II) |
title_full | Dichlorido(2,3-di-2-pyridylpyrazine-κ(2)
N
(2),N
(3))palladium(II) |
title_fullStr | Dichlorido(2,3-di-2-pyridylpyrazine-κ(2)
N
(2),N
(3))palladium(II) |
title_full_unstemmed | Dichlorido(2,3-di-2-pyridylpyrazine-κ(2)
N
(2),N
(3))palladium(II) |
title_short | Dichlorido(2,3-di-2-pyridylpyrazine-κ(2)
N
(2),N
(3))palladium(II) |
title_sort | dichlorido(2,3-di-2-pyridylpyrazine-κ(2)
n
(2),n
(3))palladium(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247536/ https://www.ncbi.nlm.nih.gov/pubmed/22219841 http://dx.doi.org/10.1107/S1600536811043753 |
work_keys_str_mv | AT hakwang dichlorido23di2pyridylpyrazinek2n2n3palladiumii |