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Dichlorido(2,3-di-2-pyridyl­pyrazine-κ(2) N (2),N (3))palladium(II)

The Pd(II) ion in the title complex, [PdCl(2)(C(14)H(10)N(4))], has a slightly distorted square-planar environment defined by the two pyridine N atoms of the chelating 2,3-di-2-pyridyl­pyrazine ligand and two chloride anions. The pyridine rings are considerably inclined to the least-squares plane of...

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Autor principal: Ha, Kwang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247536/
https://www.ncbi.nlm.nih.gov/pubmed/22219841
http://dx.doi.org/10.1107/S1600536811043753
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author Ha, Kwang
author_facet Ha, Kwang
author_sort Ha, Kwang
collection PubMed
description The Pd(II) ion in the title complex, [PdCl(2)(C(14)H(10)N(4))], has a slightly distorted square-planar environment defined by the two pyridine N atoms of the chelating 2,3-di-2-pyridyl­pyrazine ligand and two chloride anions. The pyridine rings are considerably inclined to the least-squares plane of the PdCl(2)N(2) unit [maximum deviation = 0.073 (1) Å], with dihedral angles of 64.19 (9) and 66.55 (9)°. The pyrazine ring is almost perpendicular to this plane and the dihedral angle is 88.2 (1)°. Two independent inter­molecular C—H⋯Cl hydrogen bonds, both involving the same Cl atom as a hydrogen-bond acceptor, give rise to chains running along the a and b axes, generating a layer structure extending parallel to (001). Mol­ecules are stacked in columns along the a axis. Along the b axis, successive mol­ecules stack in opposite directions.
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spelling pubmed-32475362012-01-04 Dichlorido(2,3-di-2-pyridyl­pyrazine-κ(2) N (2),N (3))palladium(II) Ha, Kwang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The Pd(II) ion in the title complex, [PdCl(2)(C(14)H(10)N(4))], has a slightly distorted square-planar environment defined by the two pyridine N atoms of the chelating 2,3-di-2-pyridyl­pyrazine ligand and two chloride anions. The pyridine rings are considerably inclined to the least-squares plane of the PdCl(2)N(2) unit [maximum deviation = 0.073 (1) Å], with dihedral angles of 64.19 (9) and 66.55 (9)°. The pyrazine ring is almost perpendicular to this plane and the dihedral angle is 88.2 (1)°. Two independent inter­molecular C—H⋯Cl hydrogen bonds, both involving the same Cl atom as a hydrogen-bond acceptor, give rise to chains running along the a and b axes, generating a layer structure extending parallel to (001). Mol­ecules are stacked in columns along the a axis. Along the b axis, successive mol­ecules stack in opposite directions. International Union of Crystallography 2011-10-29 /pmc/articles/PMC3247536/ /pubmed/22219841 http://dx.doi.org/10.1107/S1600536811043753 Text en © Kwang Ha 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Ha, Kwang
Dichlorido(2,3-di-2-pyridyl­pyrazine-κ(2) N (2),N (3))palladium(II)
title Dichlorido(2,3-di-2-pyridyl­pyrazine-κ(2) N (2),N (3))palladium(II)
title_full Dichlorido(2,3-di-2-pyridyl­pyrazine-κ(2) N (2),N (3))palladium(II)
title_fullStr Dichlorido(2,3-di-2-pyridyl­pyrazine-κ(2) N (2),N (3))palladium(II)
title_full_unstemmed Dichlorido(2,3-di-2-pyridyl­pyrazine-κ(2) N (2),N (3))palladium(II)
title_short Dichlorido(2,3-di-2-pyridyl­pyrazine-κ(2) N (2),N (3))palladium(II)
title_sort dichlorido(2,3-di-2-pyridyl­pyrazine-κ(2) n (2),n (3))palladium(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247536/
https://www.ncbi.nlm.nih.gov/pubmed/22219841
http://dx.doi.org/10.1107/S1600536811043753
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