(2-{[1-(Pyridin-2-yl)ethyl­idene]amino­meth­yl}pyridine-κ(3) N,N′,N′′)bis­(thio­cyanato-κN)zinc

The complete mol­ecule of the title mononuclear zinc(II) complex, [Zn(NCS)(2)(C(13)H(13)N(3))], is generated by crystallographic twofold symmetry, with the metal atom lying on the rotation axis. The pendant methyl group of the ligand is statistically disordered over two sites. The Zn(2+) cation is c...

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Detalles Bibliográficos
Autores principales: Wang, Chen-Yi, Li, Jing-Fen, Wu, Xiang, Tu, Hai-Yu, Zhu, Pei-Fei
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247537/
https://www.ncbi.nlm.nih.gov/pubmed/22219842
http://dx.doi.org/10.1107/S1600536811043984
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author Wang, Chen-Yi
Li, Jing-Fen
Wu, Xiang
Tu, Hai-Yu
Zhu, Pei-Fei
author_facet Wang, Chen-Yi
Li, Jing-Fen
Wu, Xiang
Tu, Hai-Yu
Zhu, Pei-Fei
author_sort Wang, Chen-Yi
collection PubMed
description The complete mol­ecule of the title mononuclear zinc(II) complex, [Zn(NCS)(2)(C(13)H(13)N(3))], is generated by crystallographic twofold symmetry, with the metal atom lying on the rotation axis. The pendant methyl group of the ligand is statistically disordered over two sites. The Zn(2+) cation is coordinated by the N,N′,N′′-tridentate Schiff base ligand, and by two thio­cyanate N atoms, forming a distorted ZnN(5) trigonal–bipyramidal geometry.
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spelling pubmed-32475372012-01-04 (2-{[1-(Pyridin-2-yl)ethyl­idene]amino­meth­yl}pyridine-κ(3) N,N′,N′′)bis­(thio­cyanato-κN)zinc Wang, Chen-Yi Li, Jing-Fen Wu, Xiang Tu, Hai-Yu Zhu, Pei-Fei Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The complete mol­ecule of the title mononuclear zinc(II) complex, [Zn(NCS)(2)(C(13)H(13)N(3))], is generated by crystallographic twofold symmetry, with the metal atom lying on the rotation axis. The pendant methyl group of the ligand is statistically disordered over two sites. The Zn(2+) cation is coordinated by the N,N′,N′′-tridentate Schiff base ligand, and by two thio­cyanate N atoms, forming a distorted ZnN(5) trigonal–bipyramidal geometry. International Union of Crystallography 2011-10-29 /pmc/articles/PMC3247537/ /pubmed/22219842 http://dx.doi.org/10.1107/S1600536811043984 Text en © Wang et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wang, Chen-Yi
Li, Jing-Fen
Wu, Xiang
Tu, Hai-Yu
Zhu, Pei-Fei
(2-{[1-(Pyridin-2-yl)ethyl­idene]amino­meth­yl}pyridine-κ(3) N,N′,N′′)bis­(thio­cyanato-κN)zinc
title (2-{[1-(Pyridin-2-yl)ethyl­idene]amino­meth­yl}pyridine-κ(3) N,N′,N′′)bis­(thio­cyanato-κN)zinc
title_full (2-{[1-(Pyridin-2-yl)ethyl­idene]amino­meth­yl}pyridine-κ(3) N,N′,N′′)bis­(thio­cyanato-κN)zinc
title_fullStr (2-{[1-(Pyridin-2-yl)ethyl­idene]amino­meth­yl}pyridine-κ(3) N,N′,N′′)bis­(thio­cyanato-κN)zinc
title_full_unstemmed (2-{[1-(Pyridin-2-yl)ethyl­idene]amino­meth­yl}pyridine-κ(3) N,N′,N′′)bis­(thio­cyanato-κN)zinc
title_short (2-{[1-(Pyridin-2-yl)ethyl­idene]amino­meth­yl}pyridine-κ(3) N,N′,N′′)bis­(thio­cyanato-κN)zinc
title_sort (2-{[1-(pyridin-2-yl)ethyl­idene]amino­meth­yl}pyridine-κ(3) n,n′,n′′)bis­(thio­cyanato-κn)zinc
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247537/
https://www.ncbi.nlm.nih.gov/pubmed/22219842
http://dx.doi.org/10.1107/S1600536811043984
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