Cargando…

catena-Poly[diaqua­(cis-cyclo­hexane-1,2-dicarboxyl­ato)cadmium]

In the title polymer, [Cd(C(8)H(10)O(4))(H(2)O)(2)](n), the Cd(II) cation is coordinated by five carboxyl­ate O atoms from three different cyclo­hexane-1,2-dicarboxyl­ate anions and two O atoms from two water mol­ecules, displaying a distorted CdO(7) pentagonal–bipyramidal geometry. Each anion acts...

Descripción completa

Detalles Bibliográficos
Autores principales: Zhu, Xiao-Hong, Cheng, Xiao-Chun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247538/
https://www.ncbi.nlm.nih.gov/pubmed/22219843
http://dx.doi.org/10.1107/S1600536811044187
Descripción
Sumario:In the title polymer, [Cd(C(8)H(10)O(4))(H(2)O)(2)](n), the Cd(II) cation is coordinated by five carboxyl­ate O atoms from three different cyclo­hexane-1,2-dicarboxyl­ate anions and two O atoms from two water mol­ecules, displaying a distorted CdO(7) pentagonal–bipyramidal geometry. Each anion acts as a μ(3)-bridge, linking symmetry-related Cd(II) ions into a layer parallel to (010). In the crystal, numerous O—H⋯O and C—H⋯O hydrogen bonds occur. The coordinated water mol­ecules and carboxyl­ate O atoms act as donors or acceptors in the formation of these hydrogen-bonding inter­actions.