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catena-Poly[diaqua­(cis-cyclo­hexane-1,2-dicarboxyl­ato)cadmium]

In the title polymer, [Cd(C(8)H(10)O(4))(H(2)O)(2)](n), the Cd(II) cation is coordinated by five carboxyl­ate O atoms from three different cyclo­hexane-1,2-dicarboxyl­ate anions and two O atoms from two water mol­ecules, displaying a distorted CdO(7) pentagonal–bipyramidal geometry. Each anion acts...

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Detalles Bibliográficos
Autores principales: Zhu, Xiao-Hong, Cheng, Xiao-Chun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247538/
https://www.ncbi.nlm.nih.gov/pubmed/22219843
http://dx.doi.org/10.1107/S1600536811044187
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author Zhu, Xiao-Hong
Cheng, Xiao-Chun
author_facet Zhu, Xiao-Hong
Cheng, Xiao-Chun
author_sort Zhu, Xiao-Hong
collection PubMed
description In the title polymer, [Cd(C(8)H(10)O(4))(H(2)O)(2)](n), the Cd(II) cation is coordinated by five carboxyl­ate O atoms from three different cyclo­hexane-1,2-dicarboxyl­ate anions and two O atoms from two water mol­ecules, displaying a distorted CdO(7) pentagonal–bipyramidal geometry. Each anion acts as a μ(3)-bridge, linking symmetry-related Cd(II) ions into a layer parallel to (010). In the crystal, numerous O—H⋯O and C—H⋯O hydrogen bonds occur. The coordinated water mol­ecules and carboxyl­ate O atoms act as donors or acceptors in the formation of these hydrogen-bonding inter­actions.
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spelling pubmed-32475382012-01-04 catena-Poly[diaqua­(cis-cyclo­hexane-1,2-dicarboxyl­ato)cadmium] Zhu, Xiao-Hong Cheng, Xiao-Chun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title polymer, [Cd(C(8)H(10)O(4))(H(2)O)(2)](n), the Cd(II) cation is coordinated by five carboxyl­ate O atoms from three different cyclo­hexane-1,2-dicarboxyl­ate anions and two O atoms from two water mol­ecules, displaying a distorted CdO(7) pentagonal–bipyramidal geometry. Each anion acts as a μ(3)-bridge, linking symmetry-related Cd(II) ions into a layer parallel to (010). In the crystal, numerous O—H⋯O and C—H⋯O hydrogen bonds occur. The coordinated water mol­ecules and carboxyl­ate O atoms act as donors or acceptors in the formation of these hydrogen-bonding inter­actions. International Union of Crystallography 2011-10-29 /pmc/articles/PMC3247538/ /pubmed/22219843 http://dx.doi.org/10.1107/S1600536811044187 Text en © Zhu and Cheng 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zhu, Xiao-Hong
Cheng, Xiao-Chun
catena-Poly[diaqua­(cis-cyclo­hexane-1,2-dicarboxyl­ato)cadmium]
title catena-Poly[diaqua­(cis-cyclo­hexane-1,2-dicarboxyl­ato)cadmium]
title_full catena-Poly[diaqua­(cis-cyclo­hexane-1,2-dicarboxyl­ato)cadmium]
title_fullStr catena-Poly[diaqua­(cis-cyclo­hexane-1,2-dicarboxyl­ato)cadmium]
title_full_unstemmed catena-Poly[diaqua­(cis-cyclo­hexane-1,2-dicarboxyl­ato)cadmium]
title_short catena-Poly[diaqua­(cis-cyclo­hexane-1,2-dicarboxyl­ato)cadmium]
title_sort catena-poly[diaqua­(cis-cyclo­hexane-1,2-dicarboxyl­ato)cadmium]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247538/
https://www.ncbi.nlm.nih.gov/pubmed/22219843
http://dx.doi.org/10.1107/S1600536811044187
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