Cargando…

(R)-N-(Ferrocenylmeth­yl)-1-hy­droxy-3-phenyl­propan-2-aminium (E)-but-2-enoate

The crystal structure of the title salt, [Fe(C(5)H(5))(C(15)H(19)NO)](C(4)H(5)O(2)), consists of discrete ammonium and carboxyl­ate ions, which associate into infinite chains parallel to [100] by means of N—H⋯O and O—H⋯O inter­actions. These chains are further cross-linked into a three-dimensional n...

Descripción completa

Detalles Bibliográficos
Autores principales: Štěpnička, Petr, Císařová, Ivana
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247540/
https://www.ncbi.nlm.nih.gov/pubmed/22219845
http://dx.doi.org/10.1107/S1600536811044096
Descripción
Sumario:The crystal structure of the title salt, [Fe(C(5)H(5))(C(15)H(19)NO)](C(4)H(5)O(2)), consists of discrete ammonium and carboxyl­ate ions, which associate into infinite chains parallel to [100] by means of N—H⋯O and O—H⋯O inter­actions. These chains are further cross-linked into a three-dimensional network by additional C—H⋯O contacts and by offset π–π stacking inter­actions of inversion-related aromatic rings [centroid–centroid distance = 3.7040 (14) Å]. The mol­ecular parameters of the ionic components are in no way unexpected, the geometry of the ammonium cation being similar to that found in other structurally characterized salts obtained from N-ferrocenylmethyl β-amino­alcohols. The (E)-but-2-enoate anion consists of two approximately planar subunits, viz the delocalized carboxyl­ate unit and the butenyl group (the latter being planar within ca. 0.002 Å), which are mutually rotated by 30.3 (4)°.