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Bis(μ-4-bromobenzoato)-κ(3) O,O′:O′;O:O,O′-bis[μ-1,3-bis(pyridin-4-yl)propane-κ(2) N:N′]bis[(4-bromobenzoato-κ(2) O,O′)cadmium]
The dinuclear complex, [Cd(2)(C(7)H(4)BrO(2))(4)(C(13)H(14)N(2))(2)], lies on a twofold rotation axis crossing midway between the two metal atoms. The Cd(II) cation is seven-coordinated with a geometry that can be considered as distorted pentagonal bipyramidal, with the N atom of the N-heterocyclic...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247541/ https://www.ncbi.nlm.nih.gov/pubmed/22219846 http://dx.doi.org/10.1107/S1600536811043996 |
Sumario: | The dinuclear complex, [Cd(2)(C(7)H(4)BrO(2))(4)(C(13)H(14)N(2))(2)], lies on a twofold rotation axis crossing midway between the two metal atoms. The Cd(II) cation is seven-coordinated with a geometry that can be considered as distorted pentagonal bipyramidal, with the N atom of the N-heterocyclic units occupying the apical sites and the O atoms of the 4-bromobenzoate units in the equatorial plane. The middle methylene group of the 1,3-bis(4-pyridyl)propane ligands is located outside of the twofold rotation axis and consequently is disordered over two sites around this symmetry element with fixed occupancies factors of 0.5. |
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