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Bis(μ-4-bromobenzoato)-κ(3) O,O′:O′;O:O,O′-bis[μ-1,3-bis(pyridin-4-yl)propane-κ(2) N:N′]bis[(4-bromobenzoato-κ(2) O,O′)cadmium]
The dinuclear complex, [Cd(2)(C(7)H(4)BrO(2))(4)(C(13)H(14)N(2))(2)], lies on a twofold rotation axis crossing midway between the two metal atoms. The Cd(II) cation is seven-coordinated with a geometry that can be considered as distorted pentagonal bipyramidal, with the N atom of the N-heterocyclic...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2011
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247541/ https://www.ncbi.nlm.nih.gov/pubmed/22219846 http://dx.doi.org/10.1107/S1600536811043996 |
| _version_ | 1782220130868002816 |
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| author | Liu, Dong Zi, Yan-Qin Ng, Seik Weng |
| author_facet | Liu, Dong Zi, Yan-Qin Ng, Seik Weng |
| author_sort | Liu, Dong |
| collection | PubMed |
| description | The dinuclear complex, [Cd(2)(C(7)H(4)BrO(2))(4)(C(13)H(14)N(2))(2)], lies on a twofold rotation axis crossing midway between the two metal atoms. The Cd(II) cation is seven-coordinated with a geometry that can be considered as distorted pentagonal bipyramidal, with the N atom of the N-heterocyclic units occupying the apical sites and the O atoms of the 4-bromobenzoate units in the equatorial plane. The middle methylene group of the 1,3-bis(4-pyridyl)propane ligands is located outside of the twofold rotation axis and consequently is disordered over two sites around this symmetry element with fixed occupancies factors of 0.5. |
| format | Online Article Text |
| id | pubmed-3247541 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2011 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-32475412012-01-04 Bis(μ-4-bromobenzoato)-κ(3) O,O′:O′;O:O,O′-bis[μ-1,3-bis(pyridin-4-yl)propane-κ(2) N:N′]bis[(4-bromobenzoato-κ(2) O,O′)cadmium] Liu, Dong Zi, Yan-Qin Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The dinuclear complex, [Cd(2)(C(7)H(4)BrO(2))(4)(C(13)H(14)N(2))(2)], lies on a twofold rotation axis crossing midway between the two metal atoms. The Cd(II) cation is seven-coordinated with a geometry that can be considered as distorted pentagonal bipyramidal, with the N atom of the N-heterocyclic units occupying the apical sites and the O atoms of the 4-bromobenzoate units in the equatorial plane. The middle methylene group of the 1,3-bis(4-pyridyl)propane ligands is located outside of the twofold rotation axis and consequently is disordered over two sites around this symmetry element with fixed occupancies factors of 0.5. International Union of Crystallography 2011-10-29 /pmc/articles/PMC3247541/ /pubmed/22219846 http://dx.doi.org/10.1107/S1600536811043996 Text en © Liu et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Liu, Dong Zi, Yan-Qin Ng, Seik Weng Bis(μ-4-bromobenzoato)-κ(3) O,O′:O′;O:O,O′-bis[μ-1,3-bis(pyridin-4-yl)propane-κ(2) N:N′]bis[(4-bromobenzoato-κ(2) O,O′)cadmium] |
| title | Bis(μ-4-bromobenzoato)-κ(3)
O,O′:O′;O:O,O′-bis[μ-1,3-bis(pyridin-4-yl)propane-κ(2)
N:N′]bis[(4-bromobenzoato-κ(2)
O,O′)cadmium] |
| title_full | Bis(μ-4-bromobenzoato)-κ(3)
O,O′:O′;O:O,O′-bis[μ-1,3-bis(pyridin-4-yl)propane-κ(2)
N:N′]bis[(4-bromobenzoato-κ(2)
O,O′)cadmium] |
| title_fullStr | Bis(μ-4-bromobenzoato)-κ(3)
O,O′:O′;O:O,O′-bis[μ-1,3-bis(pyridin-4-yl)propane-κ(2)
N:N′]bis[(4-bromobenzoato-κ(2)
O,O′)cadmium] |
| title_full_unstemmed | Bis(μ-4-bromobenzoato)-κ(3)
O,O′:O′;O:O,O′-bis[μ-1,3-bis(pyridin-4-yl)propane-κ(2)
N:N′]bis[(4-bromobenzoato-κ(2)
O,O′)cadmium] |
| title_short | Bis(μ-4-bromobenzoato)-κ(3)
O,O′:O′;O:O,O′-bis[μ-1,3-bis(pyridin-4-yl)propane-κ(2)
N:N′]bis[(4-bromobenzoato-κ(2)
O,O′)cadmium] |
| title_sort | bis(μ-4-bromobenzoato)-κ(3)
o,o′:o′;o:o,o′-bis[μ-1,3-bis(pyridin-4-yl)propane-κ(2)
n:n′]bis[(4-bromobenzoato-κ(2)
o,o′)cadmium] |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247541/ https://www.ncbi.nlm.nih.gov/pubmed/22219846 http://dx.doi.org/10.1107/S1600536811043996 |
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