Bis[5-(4-bromo­phen­yl)-4-(tert-but­oxy­carbon­yl)pyrrolidine-2-carboxyl­ato]copper(II) dihydrate

In the title compound, [Cu(C(16)H(19)BrNO(4))(2)]·2H(2)O, the Cu(II) ion resides on an inversion centre and is coordinated by two O and two N atoms from two enanti­omeric 5-(4-bromo­phen­yl)-4-(tert-but­oxy­carbon­yl)pyrrolidine-2-carboxyl­ate ligands in a distorted square-planar geometry. The relat...

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Detalles Bibliográficos
Autores principales: Kudryavtsev, Konstantin V., Churakov, Andrei V., Dogan, Ozdemir
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247543/
https://www.ncbi.nlm.nih.gov/pubmed/22219848
http://dx.doi.org/10.1107/S1600536811043893
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author Kudryavtsev, Konstantin V.
Churakov, Andrei V.
Dogan, Ozdemir
author_facet Kudryavtsev, Konstantin V.
Churakov, Andrei V.
Dogan, Ozdemir
author_sort Kudryavtsev, Konstantin V.
collection PubMed
description In the title compound, [Cu(C(16)H(19)BrNO(4))(2)]·2H(2)O, the Cu(II) ion resides on an inversion centre and is coordinated by two O and two N atoms from two enanti­omeric 5-(4-bromo­phen­yl)-4-(tert-but­oxy­carbon­yl)pyrrolidine-2-carboxyl­ate ligands in a distorted square-planar geometry. The relative stereochemistry of the three stereogenic C atoms in each ligand has been determined. In the crystal, inter­molecular N—H⋯O and O—H⋯O hydrogen bonds link the mol­ecules into layers parallel to the bc plane. The crystal studied was twinned by pseudo­merohedry with twin fractions of 0.719 (3) and 0.281 (3).
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spelling pubmed-32475432012-01-04 Bis[5-(4-bromo­phen­yl)-4-(tert-but­oxy­carbon­yl)pyrrolidine-2-carboxyl­ato]copper(II) dihydrate Kudryavtsev, Konstantin V. Churakov, Andrei V. Dogan, Ozdemir Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cu(C(16)H(19)BrNO(4))(2)]·2H(2)O, the Cu(II) ion resides on an inversion centre and is coordinated by two O and two N atoms from two enanti­omeric 5-(4-bromo­phen­yl)-4-(tert-but­oxy­carbon­yl)pyrrolidine-2-carboxyl­ate ligands in a distorted square-planar geometry. The relative stereochemistry of the three stereogenic C atoms in each ligand has been determined. In the crystal, inter­molecular N—H⋯O and O—H⋯O hydrogen bonds link the mol­ecules into layers parallel to the bc plane. The crystal studied was twinned by pseudo­merohedry with twin fractions of 0.719 (3) and 0.281 (3). International Union of Crystallography 2011-10-29 /pmc/articles/PMC3247543/ /pubmed/22219848 http://dx.doi.org/10.1107/S1600536811043893 Text en © Kudryavtsev et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Kudryavtsev, Konstantin V.
Churakov, Andrei V.
Dogan, Ozdemir
Bis[5-(4-bromo­phen­yl)-4-(tert-but­oxy­carbon­yl)pyrrolidine-2-carboxyl­ato]copper(II) dihydrate
title Bis[5-(4-bromo­phen­yl)-4-(tert-but­oxy­carbon­yl)pyrrolidine-2-carboxyl­ato]copper(II) dihydrate
title_full Bis[5-(4-bromo­phen­yl)-4-(tert-but­oxy­carbon­yl)pyrrolidine-2-carboxyl­ato]copper(II) dihydrate
title_fullStr Bis[5-(4-bromo­phen­yl)-4-(tert-but­oxy­carbon­yl)pyrrolidine-2-carboxyl­ato]copper(II) dihydrate
title_full_unstemmed Bis[5-(4-bromo­phen­yl)-4-(tert-but­oxy­carbon­yl)pyrrolidine-2-carboxyl­ato]copper(II) dihydrate
title_short Bis[5-(4-bromo­phen­yl)-4-(tert-but­oxy­carbon­yl)pyrrolidine-2-carboxyl­ato]copper(II) dihydrate
title_sort bis[5-(4-bromo­phen­yl)-4-(tert-but­oxy­carbon­yl)pyrrolidine-2-carboxyl­ato]copper(ii) dihydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247543/
https://www.ncbi.nlm.nih.gov/pubmed/22219848
http://dx.doi.org/10.1107/S1600536811043893
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AT doganozdemir bis54bromophenyl4tertbutoxycarbonylpyrrolidine2carboxylatocopperiidihydrate

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