Dichlorido{2-[(3,4-dimethylphenyl)iminomethyl]pyridine-κ(2) N,N′}copper(II)
In the title complex, [CuCl(2)(C(14)H(14)N(2))], the Cu(II) atom exhibits a very distorted tetrahedral coordination geometry involving two chloride ions and two N-atom donors from the Schiff base ligand. The range for the six bond angles about the Cu(2+) cation is 81.49 (11)–145.95 (9)°. The chelat...
Autores principales: | , , , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247544/ https://www.ncbi.nlm.nih.gov/pubmed/22219849 http://dx.doi.org/10.1107/S160053681104390X |
_version_ | 1782220131553771520 |
---|---|
author | Khalaj, Mehdi Dehghanpour, Saeed Salehzadeh, Sadegh Mahmoudi, Ali |
author_facet | Khalaj, Mehdi Dehghanpour, Saeed Salehzadeh, Sadegh Mahmoudi, Ali |
author_sort | Khalaj, Mehdi |
collection | PubMed |
description | In the title complex, [CuCl(2)(C(14)H(14)N(2))], the Cu(II) atom exhibits a very distorted tetrahedral coordination geometry involving two chloride ions and two N-atom donors from the Schiff base ligand. The range for the six bond angles about the Cu(2+) cation is 81.49 (11)–145.95 (9)°. The chelate ring including the Cu(II) atom is approximately planar, with a maximum deviation of 0.039 (4) Å for one of the C atoms; this plane forms a dihedral angle of 46.69 (9)° with the CuCl(2) plane. |
format | Online Article Text |
id | pubmed-3247544 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32475442012-01-04 Dichlorido{2-[(3,4-dimethylphenyl)iminomethyl]pyridine-κ(2) N,N′}copper(II) Khalaj, Mehdi Dehghanpour, Saeed Salehzadeh, Sadegh Mahmoudi, Ali Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [CuCl(2)(C(14)H(14)N(2))], the Cu(II) atom exhibits a very distorted tetrahedral coordination geometry involving two chloride ions and two N-atom donors from the Schiff base ligand. The range for the six bond angles about the Cu(2+) cation is 81.49 (11)–145.95 (9)°. The chelate ring including the Cu(II) atom is approximately planar, with a maximum deviation of 0.039 (4) Å for one of the C atoms; this plane forms a dihedral angle of 46.69 (9)° with the CuCl(2) plane. International Union of Crystallography 2011-10-29 /pmc/articles/PMC3247544/ /pubmed/22219849 http://dx.doi.org/10.1107/S160053681104390X Text en © Khalaj et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Khalaj, Mehdi Dehghanpour, Saeed Salehzadeh, Sadegh Mahmoudi, Ali Dichlorido{2-[(3,4-dimethylphenyl)iminomethyl]pyridine-κ(2) N,N′}copper(II) |
title | Dichlorido{2-[(3,4-dimethylphenyl)iminomethyl]pyridine-κ(2)
N,N′}copper(II) |
title_full | Dichlorido{2-[(3,4-dimethylphenyl)iminomethyl]pyridine-κ(2)
N,N′}copper(II) |
title_fullStr | Dichlorido{2-[(3,4-dimethylphenyl)iminomethyl]pyridine-κ(2)
N,N′}copper(II) |
title_full_unstemmed | Dichlorido{2-[(3,4-dimethylphenyl)iminomethyl]pyridine-κ(2)
N,N′}copper(II) |
title_short | Dichlorido{2-[(3,4-dimethylphenyl)iminomethyl]pyridine-κ(2)
N,N′}copper(II) |
title_sort | dichlorido{2-[(3,4-dimethylphenyl)iminomethyl]pyridine-κ(2)
n,n′}copper(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247544/ https://www.ncbi.nlm.nih.gov/pubmed/22219849 http://dx.doi.org/10.1107/S160053681104390X |
work_keys_str_mv | AT khalajmehdi dichlorido234dimethylphenyliminomethylpyridinek2nncopperii AT dehghanpoursaeed dichlorido234dimethylphenyliminomethylpyridinek2nncopperii AT salehzadehsadegh dichlorido234dimethylphenyliminomethylpyridinek2nncopperii AT mahmoudiali dichlorido234dimethylphenyliminomethylpyridinek2nncopperii |