Dichlorido{2-[(3,4-dimethyl­phen­yl)imino­meth­yl]pyridine-κ(2) N,N′}copper(II)

In the title complex, [CuCl(2)(C(14)H(14)N(2))], the Cu(II) atom exhibits a very distorted tetra­hedral coordination geometry involving two chloride ions and two N-atom donors from the Schiff base ligand. The range for the six bond angles about the Cu(2+) cation is 81.49 (11)–145.95 (9)°. The chelat...

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Autores principales: Khalaj, Mehdi, Dehghanpour, Saeed, Salehzadeh, Sadegh, Mahmoudi, Ali
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247544/
https://www.ncbi.nlm.nih.gov/pubmed/22219849
http://dx.doi.org/10.1107/S160053681104390X
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author Khalaj, Mehdi
Dehghanpour, Saeed
Salehzadeh, Sadegh
Mahmoudi, Ali
author_facet Khalaj, Mehdi
Dehghanpour, Saeed
Salehzadeh, Sadegh
Mahmoudi, Ali
author_sort Khalaj, Mehdi
collection PubMed
description In the title complex, [CuCl(2)(C(14)H(14)N(2))], the Cu(II) atom exhibits a very distorted tetra­hedral coordination geometry involving two chloride ions and two N-atom donors from the Schiff base ligand. The range for the six bond angles about the Cu(2+) cation is 81.49 (11)–145.95 (9)°. The chelate ring including the Cu(II) atom is approximately planar, with a maximum deviation of 0.039 (4) Å for one of the C atoms; this plane forms a dihedral angle of 46.69 (9)° with the CuCl(2) plane.
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spelling pubmed-32475442012-01-04 Dichlorido{2-[(3,4-dimethyl­phen­yl)imino­meth­yl]pyridine-κ(2) N,N′}copper(II) Khalaj, Mehdi Dehghanpour, Saeed Salehzadeh, Sadegh Mahmoudi, Ali Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [CuCl(2)(C(14)H(14)N(2))], the Cu(II) atom exhibits a very distorted tetra­hedral coordination geometry involving two chloride ions and two N-atom donors from the Schiff base ligand. The range for the six bond angles about the Cu(2+) cation is 81.49 (11)–145.95 (9)°. The chelate ring including the Cu(II) atom is approximately planar, with a maximum deviation of 0.039 (4) Å for one of the C atoms; this plane forms a dihedral angle of 46.69 (9)° with the CuCl(2) plane. International Union of Crystallography 2011-10-29 /pmc/articles/PMC3247544/ /pubmed/22219849 http://dx.doi.org/10.1107/S160053681104390X Text en © Khalaj et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Khalaj, Mehdi
Dehghanpour, Saeed
Salehzadeh, Sadegh
Mahmoudi, Ali
Dichlorido{2-[(3,4-dimethyl­phen­yl)imino­meth­yl]pyridine-κ(2) N,N′}copper(II)
title Dichlorido{2-[(3,4-dimethyl­phen­yl)imino­meth­yl]pyridine-κ(2) N,N′}copper(II)
title_full Dichlorido{2-[(3,4-dimethyl­phen­yl)imino­meth­yl]pyridine-κ(2) N,N′}copper(II)
title_fullStr Dichlorido{2-[(3,4-dimethyl­phen­yl)imino­meth­yl]pyridine-κ(2) N,N′}copper(II)
title_full_unstemmed Dichlorido{2-[(3,4-dimethyl­phen­yl)imino­meth­yl]pyridine-κ(2) N,N′}copper(II)
title_short Dichlorido{2-[(3,4-dimethyl­phen­yl)imino­meth­yl]pyridine-κ(2) N,N′}copper(II)
title_sort dichlorido{2-[(3,4-dimethyl­phen­yl)imino­meth­yl]pyridine-κ(2) n,n′}copper(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247544/
https://www.ncbi.nlm.nih.gov/pubmed/22219849
http://dx.doi.org/10.1107/S160053681104390X
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