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(2,3-Di-2-pyridylpyrazine-κ(2) N (2),N (3))diiodidopalladium(II)
The Pd(II) ion in the title complex, [PdI(2)(C(14)H(10)N(4))], is four-coordinated in a slightly distorted square-planar environment by the two pyridine N atoms of the chelating 2,3-di-2-pyridylpyrazine (dpp) ligand and two iodide anions. In the crystal, the pyridine rings are considerably inclined...
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247546/ https://www.ncbi.nlm.nih.gov/pubmed/22219851 http://dx.doi.org/10.1107/S1600536811044023 |
Sumario: | The Pd(II) ion in the title complex, [PdI(2)(C(14)H(10)N(4))], is four-coordinated in a slightly distorted square-planar environment by the two pyridine N atoms of the chelating 2,3-di-2-pyridylpyrazine (dpp) ligand and two iodide anions. In the crystal, the pyridine rings are considerably inclined to the least-squares plane of the PdI(2)N(2) unit [maximum deviation = 0.090 (2) Å], making dihedral angles of 65.0 (2) and 66.6 (2)°. The pyrazine ring is perpendicular to the unit plane, with a dihedral angle of 89.9 (2)°. The complex molecules are connected by C—H⋯I hydrogen bonds, forming a helical chain along the b axis. |
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