(μ-Piperazine-1,4-dicarbodithio­ato-κ(4) S (1),S (1′):S (4),S (4′))bis­[bis­(triphenyl­phos­phane-κP)gold(I)] chloro­form disolvate

In the title compound, [Au(2)(C(6)H(8)N(2)S(4))(C(18)H(15)P)(4)]·2CHCl(3), the digold complex resides on a crystallographic inversion center and co-crystallizes with two mol­ecules of chloro­form solvent. The piperazine-1,4-dicarbodithio­ate linker has an almost ideal chair conformation. The geometr...

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Detalles Bibliográficos
Autores principales: Guzei, Ilia A., Spencer, Lara C., Lillywhite, Stacy, Darkwa, James
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247547/
https://www.ncbi.nlm.nih.gov/pubmed/22219852
http://dx.doi.org/10.1107/S1600536811044229
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author Guzei, Ilia A.
Spencer, Lara C.
Lillywhite, Stacy
Darkwa, James
author_facet Guzei, Ilia A.
Spencer, Lara C.
Lillywhite, Stacy
Darkwa, James
author_sort Guzei, Ilia A.
collection PubMed
description In the title compound, [Au(2)(C(6)H(8)N(2)S(4))(C(18)H(15)P)(4)]·2CHCl(3), the digold complex resides on a crystallographic inversion center and co-crystallizes with two mol­ecules of chloro­form solvent. The piperazine-1,4-dicarbodithio­ate linker has an almost ideal chair conformation. The geometry about the gold atoms is severely distorted tetra­hedral punctuated by a very acute S—Au—S bite angle.
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spelling pubmed-32475472012-01-04 (μ-Piperazine-1,4-dicarbodithio­ato-κ(4) S (1),S (1′):S (4),S (4′))bis­[bis­(triphenyl­phos­phane-κP)gold(I)] chloro­form disolvate Guzei, Ilia A. Spencer, Lara C. Lillywhite, Stacy Darkwa, James Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Au(2)(C(6)H(8)N(2)S(4))(C(18)H(15)P)(4)]·2CHCl(3), the digold complex resides on a crystallographic inversion center and co-crystallizes with two mol­ecules of chloro­form solvent. The piperazine-1,4-dicarbodithio­ate linker has an almost ideal chair conformation. The geometry about the gold atoms is severely distorted tetra­hedral punctuated by a very acute S—Au—S bite angle. International Union of Crystallography 2011-10-29 /pmc/articles/PMC3247547/ /pubmed/22219852 http://dx.doi.org/10.1107/S1600536811044229 Text en © Guzei et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Guzei, Ilia A.
Spencer, Lara C.
Lillywhite, Stacy
Darkwa, James
(μ-Piperazine-1,4-dicarbodithio­ato-κ(4) S (1),S (1′):S (4),S (4′))bis­[bis­(triphenyl­phos­phane-κP)gold(I)] chloro­form disolvate
title (μ-Piperazine-1,4-dicarbodithio­ato-κ(4) S (1),S (1′):S (4),S (4′))bis­[bis­(triphenyl­phos­phane-κP)gold(I)] chloro­form disolvate
title_full (μ-Piperazine-1,4-dicarbodithio­ato-κ(4) S (1),S (1′):S (4),S (4′))bis­[bis­(triphenyl­phos­phane-κP)gold(I)] chloro­form disolvate
title_fullStr (μ-Piperazine-1,4-dicarbodithio­ato-κ(4) S (1),S (1′):S (4),S (4′))bis­[bis­(triphenyl­phos­phane-κP)gold(I)] chloro­form disolvate
title_full_unstemmed (μ-Piperazine-1,4-dicarbodithio­ato-κ(4) S (1),S (1′):S (4),S (4′))bis­[bis­(triphenyl­phos­phane-κP)gold(I)] chloro­form disolvate
title_short (μ-Piperazine-1,4-dicarbodithio­ato-κ(4) S (1),S (1′):S (4),S (4′))bis­[bis­(triphenyl­phos­phane-κP)gold(I)] chloro­form disolvate
title_sort (μ-piperazine-1,4-dicarbodithio­ato-κ(4) s (1),s (1′):s (4),s (4′))bis­[bis­(triphenyl­phos­phane-κp)gold(i)] chloro­form disolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247547/
https://www.ncbi.nlm.nih.gov/pubmed/22219852
http://dx.doi.org/10.1107/S1600536811044229
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AT lillywhitestacy mpiperazine14dicarbodithioatok4s1s1s4s4bisbistriphenylphosphanekpgoldichloroformdisolvate
AT darkwajames mpiperazine14dicarbodithioatok4s1s1s4s4bisbistriphenylphosphanekpgoldichloroformdisolvate

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