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fac-Tricarbonyl(pyridine-κN)(1,1,1-trifluoroacetylacetonato-κ(2) O,O′)rhenium(I)
In the title compound, [Re(C(5)H(4)F(3)O(2))(C(5)H(5)N)(CO)(3)], the Re(I) atom is six-coordinated owing to bonding by three carbonyl ligands arranged in a fac configuration, two O atoms from the bidentate 1,1,1-trifluoroacetylacetonate ligand and an N atom from a pyridine ligand. In the crystal,...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2011
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247548/ https://www.ncbi.nlm.nih.gov/pubmed/22219853 http://dx.doi.org/10.1107/S160053681104476X |
| _version_ | 1782220132466032640 |
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| author | Visser, Hendrik G. Roodt, Andreas Volmink, Amanda-lee Kemp, Gerdus |
| author_facet | Visser, Hendrik G. Roodt, Andreas Volmink, Amanda-lee Kemp, Gerdus |
| author_sort | Visser, Hendrik G. |
| collection | PubMed |
| description | In the title compound, [Re(C(5)H(4)F(3)O(2))(C(5)H(5)N)(CO)(3)], the Re(I) atom is six-coordinated owing to bonding by three carbonyl ligands arranged in a fac configuration, two O atoms from the bidentate 1,1,1-trifluoroacetylacetonate ligand and an N atom from a pyridine ligand. In the crystal, the molecules pack in layers, diagonally, in a head-to-tail fashion across the ab plane. These layers are stabilsed by intermolecular C—H⋯O and C—H⋯F hydrogen bonds. |
| format | Online Article Text |
| id | pubmed-3247548 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2011 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-32475482012-01-04 fac-Tricarbonyl(pyridine-κN)(1,1,1-trifluoroacetylacetonato-κ(2) O,O′)rhenium(I) Visser, Hendrik G. Roodt, Andreas Volmink, Amanda-lee Kemp, Gerdus Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Re(C(5)H(4)F(3)O(2))(C(5)H(5)N)(CO)(3)], the Re(I) atom is six-coordinated owing to bonding by three carbonyl ligands arranged in a fac configuration, two O atoms from the bidentate 1,1,1-trifluoroacetylacetonate ligand and an N atom from a pyridine ligand. In the crystal, the molecules pack in layers, diagonally, in a head-to-tail fashion across the ab plane. These layers are stabilsed by intermolecular C—H⋯O and C—H⋯F hydrogen bonds. International Union of Crystallography 2011-10-29 /pmc/articles/PMC3247548/ /pubmed/22219853 http://dx.doi.org/10.1107/S160053681104476X Text en © Visser et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Visser, Hendrik G. Roodt, Andreas Volmink, Amanda-lee Kemp, Gerdus fac-Tricarbonyl(pyridine-κN)(1,1,1-trifluoroacetylacetonato-κ(2) O,O′)rhenium(I) |
| title |
fac-Tricarbonyl(pyridine-κN)(1,1,1-trifluoroacetylacetonato-κ(2)
O,O′)rhenium(I) |
| title_full |
fac-Tricarbonyl(pyridine-κN)(1,1,1-trifluoroacetylacetonato-κ(2)
O,O′)rhenium(I) |
| title_fullStr |
fac-Tricarbonyl(pyridine-κN)(1,1,1-trifluoroacetylacetonato-κ(2)
O,O′)rhenium(I) |
| title_full_unstemmed |
fac-Tricarbonyl(pyridine-κN)(1,1,1-trifluoroacetylacetonato-κ(2)
O,O′)rhenium(I) |
| title_short |
fac-Tricarbonyl(pyridine-κN)(1,1,1-trifluoroacetylacetonato-κ(2)
O,O′)rhenium(I) |
| title_sort | fac-tricarbonyl(pyridine-κn)(1,1,1-trifluoroacetylacetonato-κ(2)
o,o′)rhenium(i) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247548/ https://www.ncbi.nlm.nih.gov/pubmed/22219853 http://dx.doi.org/10.1107/S160053681104476X |
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