Tris(pyridin-2-yl­methanol)nickel(II) hexa­fluoridophosphate trifluoro­acetate

In the crystal structure of the title complex, [Ni(C(6)H(7)NO)(3)](PF(6))(C(2)F(3)O(2)), the Ni(II) ion is in a slightly distorted octa­hedral NiO(3)N(3) coordination geometry with each of the three N and three O atoms in a meridional coordination. In the crystal, the complex mol­ecules and the trif...

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Detalles Bibliográficos
Autores principales: Hamaguchi, Tomohiko, Nagata, Tomoko, Kawata, Satoshi, Ando, Isao
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247549/
https://www.ncbi.nlm.nih.gov/pubmed/22219854
http://dx.doi.org/10.1107/S160053681104431X
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author Hamaguchi, Tomohiko
Nagata, Tomoko
Kawata, Satoshi
Ando, Isao
author_facet Hamaguchi, Tomohiko
Nagata, Tomoko
Kawata, Satoshi
Ando, Isao
author_sort Hamaguchi, Tomohiko
collection PubMed
description In the crystal structure of the title complex, [Ni(C(6)H(7)NO)(3)](PF(6))(C(2)F(3)O(2)), the Ni(II) ion is in a slightly distorted octa­hedral NiO(3)N(3) coordination geometry with each of the three N and three O atoms in a meridional coordination. In the crystal, the complex mol­ecules and the trifluoro­acetate anions are connected via O—H⋯O hydrogen bonding into layers parallel to the ab plane.
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spelling pubmed-32475492012-01-04 Tris(pyridin-2-yl­methanol)nickel(II) hexa­fluoridophosphate trifluoro­acetate Hamaguchi, Tomohiko Nagata, Tomoko Kawata, Satoshi Ando, Isao Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the crystal structure of the title complex, [Ni(C(6)H(7)NO)(3)](PF(6))(C(2)F(3)O(2)), the Ni(II) ion is in a slightly distorted octa­hedral NiO(3)N(3) coordination geometry with each of the three N and three O atoms in a meridional coordination. In the crystal, the complex mol­ecules and the trifluoro­acetate anions are connected via O—H⋯O hydrogen bonding into layers parallel to the ab plane. International Union of Crystallography 2011-10-29 /pmc/articles/PMC3247549/ /pubmed/22219854 http://dx.doi.org/10.1107/S160053681104431X Text en © Hamaguchi et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Hamaguchi, Tomohiko
Nagata, Tomoko
Kawata, Satoshi
Ando, Isao
Tris(pyridin-2-yl­methanol)nickel(II) hexa­fluoridophosphate trifluoro­acetate
title Tris(pyridin-2-yl­methanol)nickel(II) hexa­fluoridophosphate trifluoro­acetate
title_full Tris(pyridin-2-yl­methanol)nickel(II) hexa­fluoridophosphate trifluoro­acetate
title_fullStr Tris(pyridin-2-yl­methanol)nickel(II) hexa­fluoridophosphate trifluoro­acetate
title_full_unstemmed Tris(pyridin-2-yl­methanol)nickel(II) hexa­fluoridophosphate trifluoro­acetate
title_short Tris(pyridin-2-yl­methanol)nickel(II) hexa­fluoridophosphate trifluoro­acetate
title_sort tris(pyridin-2-yl­methanol)nickel(ii) hexa­fluoridophosphate trifluoro­acetate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247549/
https://www.ncbi.nlm.nih.gov/pubmed/22219854
http://dx.doi.org/10.1107/S160053681104431X
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AT kawatasatoshi trispyridin2ylmethanolnickeliihexafluoridophosphatetrifluoroacetate
AT andoisao trispyridin2ylmethanolnickeliihexafluoridophosphatetrifluoroacetate

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