Poly[bis­[μ(2)-1,4-bis­(1H-imidazol-1-yl)butane]­dichloridonickel(II)]

The asymmetric unit of the title compound, [NiCl(2)(C(10)H(14)N(4))(2)](n), consists of one Ni(2+) ion which is located on an inversion center, one 1,4-bis­(imidazol-1-yl)butane (bimb) and one chloride ion. The Ni(2+) ion exhibits a distorted octa­hedral coordination environment defined by four N at...

Descripción completa

Detalles Bibliográficos
Autores principales: Zhang, Jia, Song, Jiang-Feng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247550/
https://www.ncbi.nlm.nih.gov/pubmed/22219855
http://dx.doi.org/10.1107/S1600536811044448
Descripción
Sumario:The asymmetric unit of the title compound, [NiCl(2)(C(10)H(14)N(4))(2)](n), consists of one Ni(2+) ion which is located on an inversion center, one 1,4-bis­(imidazol-1-yl)butane (bimb) and one chloride ion. The Ni(2+) ion exhibits a distorted octa­hedral coordination environment defined by four N atoms from four bimb ligands in the equatorial plane and two chloride ions in axial positions. The bridging coordination mode of the bimb ligands leads to the formation of inter­penetrating square Ni(4)(bimb)(4) units that are arranged parallel to (001). The separation between the Ni atoms in these units is 13.740 (3) Å.

Ejemplares similares