Poly[bis­[μ(2)-1,4-bis­(1H-imidazol-1-yl)butane]­dichloridonickel(II)]

The asymmetric unit of the title compound, [NiCl(2)(C(10)H(14)N(4))(2)](n), consists of one Ni(2+) ion which is located on an inversion center, one 1,4-bis­(imidazol-1-yl)butane (bimb) and one chloride ion. The Ni(2+) ion exhibits a distorted octa­hedral coordination environment defined by four N at...

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Detalles Bibliográficos
Autores principales: Zhang, Jia, Song, Jiang-Feng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247550/
https://www.ncbi.nlm.nih.gov/pubmed/22219855
http://dx.doi.org/10.1107/S1600536811044448
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author Zhang, Jia
Song, Jiang-Feng
author_facet Zhang, Jia
Song, Jiang-Feng
author_sort Zhang, Jia
collection PubMed
description The asymmetric unit of the title compound, [NiCl(2)(C(10)H(14)N(4))(2)](n), consists of one Ni(2+) ion which is located on an inversion center, one 1,4-bis­(imidazol-1-yl)butane (bimb) and one chloride ion. The Ni(2+) ion exhibits a distorted octa­hedral coordination environment defined by four N atoms from four bimb ligands in the equatorial plane and two chloride ions in axial positions. The bridging coordination mode of the bimb ligands leads to the formation of inter­penetrating square Ni(4)(bimb)(4) units that are arranged parallel to (001). The separation between the Ni atoms in these units is 13.740 (3) Å.
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spelling pubmed-32475502012-01-04 Poly[bis­[μ(2)-1,4-bis­(1H-imidazol-1-yl)butane]­dichloridonickel(II)] Zhang, Jia Song, Jiang-Feng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, [NiCl(2)(C(10)H(14)N(4))(2)](n), consists of one Ni(2+) ion which is located on an inversion center, one 1,4-bis­(imidazol-1-yl)butane (bimb) and one chloride ion. The Ni(2+) ion exhibits a distorted octa­hedral coordination environment defined by four N atoms from four bimb ligands in the equatorial plane and two chloride ions in axial positions. The bridging coordination mode of the bimb ligands leads to the formation of inter­penetrating square Ni(4)(bimb)(4) units that are arranged parallel to (001). The separation between the Ni atoms in these units is 13.740 (3) Å. International Union of Crystallography 2011-10-29 /pmc/articles/PMC3247550/ /pubmed/22219855 http://dx.doi.org/10.1107/S1600536811044448 Text en © Zhang and Song 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zhang, Jia
Song, Jiang-Feng
Poly[bis­[μ(2)-1,4-bis­(1H-imidazol-1-yl)butane]­dichloridonickel(II)]
title Poly[bis­[μ(2)-1,4-bis­(1H-imidazol-1-yl)butane]­dichloridonickel(II)]
title_full Poly[bis­[μ(2)-1,4-bis­(1H-imidazol-1-yl)butane]­dichloridonickel(II)]
title_fullStr Poly[bis­[μ(2)-1,4-bis­(1H-imidazol-1-yl)butane]­dichloridonickel(II)]
title_full_unstemmed Poly[bis­[μ(2)-1,4-bis­(1H-imidazol-1-yl)butane]­dichloridonickel(II)]
title_short Poly[bis­[μ(2)-1,4-bis­(1H-imidazol-1-yl)butane]­dichloridonickel(II)]
title_sort poly[bis­[μ(2)-1,4-bis­(1h-imidazol-1-yl)butane]­dichloridonickel(ii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247550/
https://www.ncbi.nlm.nih.gov/pubmed/22219855
http://dx.doi.org/10.1107/S1600536811044448
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