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Dichlorido(2,3-di-2-pyridylpyrazine-κ(2) N (1),N (2))palladium(II)
The Pd(II) ion in the title complex, [PdCl(2)(C(14)H(10)N(4))], is four-coordinated in a distorted square-planar environment defined by two N atoms of a chelating 2,3-di-2-pyridylpyrazine (dpp) ligand and two chloride anions. The pyridine ring coordinated to the Pd atom is inclined slightly to its...
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Formato: | Online Artículo Texto |
Lenguaje: | English |
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International Union of Crystallography
2011
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247551/ https://www.ncbi.nlm.nih.gov/pubmed/22219856 http://dx.doi.org/10.1107/S1600536811044369 |
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author | Ha, Kwang |
author_facet | Ha, Kwang |
author_sort | Ha, Kwang |
collection | PubMed |
description | The Pd(II) ion in the title complex, [PdCl(2)(C(14)H(10)N(4))], is four-coordinated in a distorted square-planar environment defined by two N atoms of a chelating 2,3-di-2-pyridylpyrazine (dpp) ligand and two chloride anions. The pyridine ring coordinated to the Pd atom is inclined slightly to its carrier pyrazine ring [dihedral angle = 14.4 (3)°], whereas the uncoordinated pyridine ring is inclined considerably to the pyrazine ring [dihedral angle = 52.2 (2)°]. The dihedral angle between the two pyridine rings is 58.8 (2)°. In the crystal, complex molecules are connected by intermolecular C—H⋯Cl and C—H⋯N hydrogen bonds, forming a three-dimensional network. Intramolecular C—H⋯Cl hydrogen bonds are also present. |
format | Online Article Text |
id | pubmed-3247551 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32475512012-01-04 Dichlorido(2,3-di-2-pyridylpyrazine-κ(2) N (1),N (2))palladium(II) Ha, Kwang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The Pd(II) ion in the title complex, [PdCl(2)(C(14)H(10)N(4))], is four-coordinated in a distorted square-planar environment defined by two N atoms of a chelating 2,3-di-2-pyridylpyrazine (dpp) ligand and two chloride anions. The pyridine ring coordinated to the Pd atom is inclined slightly to its carrier pyrazine ring [dihedral angle = 14.4 (3)°], whereas the uncoordinated pyridine ring is inclined considerably to the pyrazine ring [dihedral angle = 52.2 (2)°]. The dihedral angle between the two pyridine rings is 58.8 (2)°. In the crystal, complex molecules are connected by intermolecular C—H⋯Cl and C—H⋯N hydrogen bonds, forming a three-dimensional network. Intramolecular C—H⋯Cl hydrogen bonds are also present. International Union of Crystallography 2011-10-29 /pmc/articles/PMC3247551/ /pubmed/22219856 http://dx.doi.org/10.1107/S1600536811044369 Text en © Kwang Ha 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Ha, Kwang Dichlorido(2,3-di-2-pyridylpyrazine-κ(2) N (1),N (2))palladium(II) |
title | Dichlorido(2,3-di-2-pyridylpyrazine-κ(2)
N
(1),N
(2))palladium(II) |
title_full | Dichlorido(2,3-di-2-pyridylpyrazine-κ(2)
N
(1),N
(2))palladium(II) |
title_fullStr | Dichlorido(2,3-di-2-pyridylpyrazine-κ(2)
N
(1),N
(2))palladium(II) |
title_full_unstemmed | Dichlorido(2,3-di-2-pyridylpyrazine-κ(2)
N
(1),N
(2))palladium(II) |
title_short | Dichlorido(2,3-di-2-pyridylpyrazine-κ(2)
N
(1),N
(2))palladium(II) |
title_sort | dichlorido(2,3-di-2-pyridylpyrazine-κ(2)
n
(1),n
(2))palladium(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247551/ https://www.ncbi.nlm.nih.gov/pubmed/22219856 http://dx.doi.org/10.1107/S1600536811044369 |
work_keys_str_mv | AT hakwang dichlorido23di2pyridylpyrazinek2n1n2palladiumii |