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Dichlorido(2,3-di-2-pyridyl­pyrazine-κ(2) N (1),N (2))palladium(II)

The Pd(II) ion in the title complex, [PdCl(2)(C(14)H(10)N(4))], is four-coordinated in a distorted square-planar environment defined by two N atoms of a chelating 2,3-di-2-pyridyl­pyrazine (dpp) ligand and two chloride anions. The pyridine ring coordinated to the Pd atom is inclined slightly to its...

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Autor principal: Ha, Kwang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247551/
https://www.ncbi.nlm.nih.gov/pubmed/22219856
http://dx.doi.org/10.1107/S1600536811044369
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author Ha, Kwang
author_facet Ha, Kwang
author_sort Ha, Kwang
collection PubMed
description The Pd(II) ion in the title complex, [PdCl(2)(C(14)H(10)N(4))], is four-coordinated in a distorted square-planar environment defined by two N atoms of a chelating 2,3-di-2-pyridyl­pyrazine (dpp) ligand and two chloride anions. The pyridine ring coordinated to the Pd atom is inclined slightly to its carrier pyrazine ring [dihedral angle = 14.4 (3)°], whereas the uncoordinated pyridine ring is inclined considerably to the pyrazine ring [dihedral angle = 52.2 (2)°]. The dihedral angle between the two pyridine rings is 58.8 (2)°. In the crystal, complex mol­ecules are connected by inter­molecular C—H⋯Cl and C—H⋯N hydrogen bonds, forming a three-dimensional network. Intra­molecular C—H⋯Cl hydrogen bonds are also present.
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spelling pubmed-32475512012-01-04 Dichlorido(2,3-di-2-pyridyl­pyrazine-κ(2) N (1),N (2))palladium(II) Ha, Kwang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The Pd(II) ion in the title complex, [PdCl(2)(C(14)H(10)N(4))], is four-coordinated in a distorted square-planar environment defined by two N atoms of a chelating 2,3-di-2-pyridyl­pyrazine (dpp) ligand and two chloride anions. The pyridine ring coordinated to the Pd atom is inclined slightly to its carrier pyrazine ring [dihedral angle = 14.4 (3)°], whereas the uncoordinated pyridine ring is inclined considerably to the pyrazine ring [dihedral angle = 52.2 (2)°]. The dihedral angle between the two pyridine rings is 58.8 (2)°. In the crystal, complex mol­ecules are connected by inter­molecular C—H⋯Cl and C—H⋯N hydrogen bonds, forming a three-dimensional network. Intra­molecular C—H⋯Cl hydrogen bonds are also present. International Union of Crystallography 2011-10-29 /pmc/articles/PMC3247551/ /pubmed/22219856 http://dx.doi.org/10.1107/S1600536811044369 Text en © Kwang Ha 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Ha, Kwang
Dichlorido(2,3-di-2-pyridyl­pyrazine-κ(2) N (1),N (2))palladium(II)
title Dichlorido(2,3-di-2-pyridyl­pyrazine-κ(2) N (1),N (2))palladium(II)
title_full Dichlorido(2,3-di-2-pyridyl­pyrazine-κ(2) N (1),N (2))palladium(II)
title_fullStr Dichlorido(2,3-di-2-pyridyl­pyrazine-κ(2) N (1),N (2))palladium(II)
title_full_unstemmed Dichlorido(2,3-di-2-pyridyl­pyrazine-κ(2) N (1),N (2))palladium(II)
title_short Dichlorido(2,3-di-2-pyridyl­pyrazine-κ(2) N (1),N (2))palladium(II)
title_sort dichlorido(2,3-di-2-pyridyl­pyrazine-κ(2) n (1),n (2))palladium(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247551/
https://www.ncbi.nlm.nih.gov/pubmed/22219856
http://dx.doi.org/10.1107/S1600536811044369
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