Diaqua­bis­(dimethyl sulfoxide-κO)­disaccharinatocadmium

The title compound, [Cd(C(7)H(4)NO(3)S)(2)(C(2)H(6)OS)(2)(H(2)O)(2)], contains a Cd(2+) cation in an octahedral coordination environment. The metal atom is surrounded by the two different neutral ligands dimethyl sulfoxide (DMSO) and water, each coordin­ating through the O atom. The anionic sacchari...

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Detalles Bibliográficos
Autores principales: Potwana, Fezile S. W., Van Zyl, Werner E.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247552/
https://www.ncbi.nlm.nih.gov/pubmed/22219857
http://dx.doi.org/10.1107/S1600536811044497
Descripción
Sumario:The title compound, [Cd(C(7)H(4)NO(3)S)(2)(C(2)H(6)OS)(2)(H(2)O)(2)], contains a Cd(2+) cation in an octahedral coordination environment. The metal atom is surrounded by the two different neutral ligands dimethyl sulfoxide (DMSO) and water, each coordin­ating through the O atom. The anionic saccharinate (sac; 1,1,3-trioxo-2,3-dihydro-1λ(6),2-benzothia­zol-2-ide) ligand coordin­ates through the N atom. Each of the three similar ligand pairs is in a trans configuration with respect to each other. The Cd atom lies on a crystallographic center of symmetry. The DMSO ligand coordinates through the lone pair of electrons on the O atom, as can be seen from the Cd—O—S bond angle of 123.96 (9)°.

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