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Diaquabis(dimethyl sulfoxide-κO)disaccharinatocadmium
The title compound, [Cd(C(7)H(4)NO(3)S)(2)(C(2)H(6)OS)(2)(H(2)O)(2)], contains a Cd(2+) cation in an octahedral coordination environment. The metal atom is surrounded by the two different neutral ligands dimethyl sulfoxide (DMSO) and water, each coordinating through the O atom. The anionic sacchari...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247552/ https://www.ncbi.nlm.nih.gov/pubmed/22219857 http://dx.doi.org/10.1107/S1600536811044497 |
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author | Potwana, Fezile S. W. Van Zyl, Werner E. |
author_facet | Potwana, Fezile S. W. Van Zyl, Werner E. |
author_sort | Potwana, Fezile S. W. |
collection | PubMed |
description | The title compound, [Cd(C(7)H(4)NO(3)S)(2)(C(2)H(6)OS)(2)(H(2)O)(2)], contains a Cd(2+) cation in an octahedral coordination environment. The metal atom is surrounded by the two different neutral ligands dimethyl sulfoxide (DMSO) and water, each coordinating through the O atom. The anionic saccharinate (sac; 1,1,3-trioxo-2,3-dihydro-1λ(6),2-benzothiazol-2-ide) ligand coordinates through the N atom. Each of the three similar ligand pairs is in a trans configuration with respect to each other. The Cd atom lies on a crystallographic center of symmetry. The DMSO ligand coordinates through the lone pair of electrons on the O atom, as can be seen from the Cd—O—S bond angle of 123.96 (9)°. |
format | Online Article Text |
id | pubmed-3247552 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32475522012-01-04 Diaquabis(dimethyl sulfoxide-κO)disaccharinatocadmium Potwana, Fezile S. W. Van Zyl, Werner E. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Cd(C(7)H(4)NO(3)S)(2)(C(2)H(6)OS)(2)(H(2)O)(2)], contains a Cd(2+) cation in an octahedral coordination environment. The metal atom is surrounded by the two different neutral ligands dimethyl sulfoxide (DMSO) and water, each coordinating through the O atom. The anionic saccharinate (sac; 1,1,3-trioxo-2,3-dihydro-1λ(6),2-benzothiazol-2-ide) ligand coordinates through the N atom. Each of the three similar ligand pairs is in a trans configuration with respect to each other. The Cd atom lies on a crystallographic center of symmetry. The DMSO ligand coordinates through the lone pair of electrons on the O atom, as can be seen from the Cd—O—S bond angle of 123.96 (9)°. International Union of Crystallography 2011-10-29 /pmc/articles/PMC3247552/ /pubmed/22219857 http://dx.doi.org/10.1107/S1600536811044497 Text en © Potwana and Van Zyl 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Potwana, Fezile S. W. Van Zyl, Werner E. Diaquabis(dimethyl sulfoxide-κO)disaccharinatocadmium |
title | Diaquabis(dimethyl sulfoxide-κO)disaccharinatocadmium |
title_full | Diaquabis(dimethyl sulfoxide-κO)disaccharinatocadmium |
title_fullStr | Diaquabis(dimethyl sulfoxide-κO)disaccharinatocadmium |
title_full_unstemmed | Diaquabis(dimethyl sulfoxide-κO)disaccharinatocadmium |
title_short | Diaquabis(dimethyl sulfoxide-κO)disaccharinatocadmium |
title_sort | diaquabis(dimethyl sulfoxide-κo)disaccharinatocadmium |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247552/ https://www.ncbi.nlm.nih.gov/pubmed/22219857 http://dx.doi.org/10.1107/S1600536811044497 |
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