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Diaqua­bis­(dimethyl sulfoxide-κO)­disaccharinatocadmium

The title compound, [Cd(C(7)H(4)NO(3)S)(2)(C(2)H(6)OS)(2)(H(2)O)(2)], contains a Cd(2+) cation in an octahedral coordination environment. The metal atom is surrounded by the two different neutral ligands dimethyl sulfoxide (DMSO) and water, each coordin­ating through the O atom. The anionic sacchari...

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Detalles Bibliográficos
Autores principales: Potwana, Fezile S. W., Van Zyl, Werner E.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247552/
https://www.ncbi.nlm.nih.gov/pubmed/22219857
http://dx.doi.org/10.1107/S1600536811044497
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author Potwana, Fezile S. W.
Van Zyl, Werner E.
author_facet Potwana, Fezile S. W.
Van Zyl, Werner E.
author_sort Potwana, Fezile S. W.
collection PubMed
description The title compound, [Cd(C(7)H(4)NO(3)S)(2)(C(2)H(6)OS)(2)(H(2)O)(2)], contains a Cd(2+) cation in an octahedral coordination environment. The metal atom is surrounded by the two different neutral ligands dimethyl sulfoxide (DMSO) and water, each coordin­ating through the O atom. The anionic saccharinate (sac; 1,1,3-trioxo-2,3-dihydro-1λ(6),2-benzothia­zol-2-ide) ligand coordin­ates through the N atom. Each of the three similar ligand pairs is in a trans configuration with respect to each other. The Cd atom lies on a crystallographic center of symmetry. The DMSO ligand coordinates through the lone pair of electrons on the O atom, as can be seen from the Cd—O—S bond angle of 123.96 (9)°.
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spelling pubmed-32475522012-01-04 Diaqua­bis­(dimethyl sulfoxide-κO)­disaccharinatocadmium Potwana, Fezile S. W. Van Zyl, Werner E. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Cd(C(7)H(4)NO(3)S)(2)(C(2)H(6)OS)(2)(H(2)O)(2)], contains a Cd(2+) cation in an octahedral coordination environment. The metal atom is surrounded by the two different neutral ligands dimethyl sulfoxide (DMSO) and water, each coordin­ating through the O atom. The anionic saccharinate (sac; 1,1,3-trioxo-2,3-dihydro-1λ(6),2-benzothia­zol-2-ide) ligand coordin­ates through the N atom. Each of the three similar ligand pairs is in a trans configuration with respect to each other. The Cd atom lies on a crystallographic center of symmetry. The DMSO ligand coordinates through the lone pair of electrons on the O atom, as can be seen from the Cd—O—S bond angle of 123.96 (9)°. International Union of Crystallography 2011-10-29 /pmc/articles/PMC3247552/ /pubmed/22219857 http://dx.doi.org/10.1107/S1600536811044497 Text en © Potwana and Van Zyl 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Potwana, Fezile S. W.
Van Zyl, Werner E.
Diaqua­bis­(dimethyl sulfoxide-κO)­disaccharinatocadmium
title Diaqua­bis­(dimethyl sulfoxide-κO)­disaccharinatocadmium
title_full Diaqua­bis­(dimethyl sulfoxide-κO)­disaccharinatocadmium
title_fullStr Diaqua­bis­(dimethyl sulfoxide-κO)­disaccharinatocadmium
title_full_unstemmed Diaqua­bis­(dimethyl sulfoxide-κO)­disaccharinatocadmium
title_short Diaqua­bis­(dimethyl sulfoxide-κO)­disaccharinatocadmium
title_sort diaqua­bis­(dimethyl sulfoxide-κo)­disaccharinatocadmium
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247552/
https://www.ncbi.nlm.nih.gov/pubmed/22219857
http://dx.doi.org/10.1107/S1600536811044497
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